Zobrazeno 1 - 6
of 6
pro vyhledávání: '"Taylor A F, Nelson"'
Autor:
Robert J. Harris, Jiyong Park, Cora E. MacBeth, Daniel C. Salgueiro, Simon B. Blakey, Nafees Iqbal, Taylor A. F. Nelson, Mu-Hyun Baik, John Bacsa
Publikováno v:
Journal of the American Chemical Society. 142:5842-5851
Herein, the mechanism of catalytic allylic C-H amination reactions promoted by Cp*Rh complexes is reported. Reaction kinetics experiments, stoichiometric studies, and DFT calculations demonstrate that the allylic C-H activation to generate a Cp*Rh(π
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::8d729291079757a42881b2bda04c7121
https://doi.org/10.1021/jacs.0c01069
https://doi.org/10.1021/jacs.0c01069
Publikováno v:
Dalton Transactions. 49:13928-13935
Allylic C-H functionalization catalysed by group 9 Cp* transition-metal complexes has recently gained significant attention. These reactions have expanded allylic C-H functionalization to include di- and trisubstituted olefins, and a broad range of c
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::3c3f154115951932cf66de7c010f823d
https://doi.org/10.1039/d0dt02313b
https://doi.org/10.1039/d0dt02313b
Publikováno v:
Dalton transactions (Cambridge, England : 2003). 49(40)
Allylic C-H functionalization catalysed by group 9 Cp* transition-metal complexes has recently gained significant attention. These reactions have expanded allylic C-H functionalization to include di- and trisubstituted olefins, and a broad range of c
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=pmid________::916dcf32592034ae8fa299e8edfae0d3
https://pubmed.ncbi.nlm.nih.gov/32909583
https://pubmed.ncbi.nlm.nih.gov/32909583
Autor:
Taylor A. F. Nelson, Simon B. Blakey
Publikováno v:
Angewandte Chemie. 130:15127-15131
Herein we report on the development of an oxidative allylic C-H etherification reaction, utilizing internal olefins and alcohols as simple precursors. Key advances include the use of RhCp* complexes to promote the allylic C-H functionalization of int
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::71f9c034f25e14db92c2850c3dcb16bd
https://doi.org/10.1002/ange.201809863
https://doi.org/10.1002/ange.201809863
Autor:
Robert J. Harris, Jiyong Park, Cora E. MacBeth, Daniel C. Salgueiro, Taylor A. F. Nelson, Mu-Hyun Baik, Simon B. Blakey, John Bacsa, Nafees Iqbal
The mechanism of catalytic allylic C–H amination reactions promoted by Cp*Rh complexes is reported. Reaction kinetics experiments, stoichiometric studies, and DFT calculations demonstrate that allylic C–H activation to generate a Cp*Rh(π-allyl)
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::d2bbb4b562d2557221b3d39cc685e9be
https://doi.org/10.26434/chemrxiv.9752807.v1
https://doi.org/10.26434/chemrxiv.9752807.v1
Publikováno v:
The Journal of organic chemistry. 84(20)
In this study we report the development of the regioselective Cp*Ir(III)-catalyzed allylic C-H sulfamidation of allylbenzene derivatives, using azides as the nitrogen source. The reaction putatively proceeds through a Cp*Ir(III)-π-allyl intermediate
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::f082a6103fdaece591808c4b44c42a2c
https://pubmed.ncbi.nlm.nih.gov/31418569
https://pubmed.ncbi.nlm.nih.gov/31418569