Synthesis with Perfect Atom Economy: Generation of Furan Derivatives by 1,3-Dipolar Cycloaddition of Acetylenedicarboxylates at Cyclooctynes

Autor: Banert, Klaus, Bochmann, Sandra, Ihle, Andreas, Plefka, Oliver, Taubert, Florian, Walther, Tina, Korb, Marcus, Rüffer, Tobias, Lang, Heinrich

Publikováno v: Banert, K.; Bochmann, S.; Ihle, A.; Plefka, O.; Taubert, F.; Walther, T.; Korb, M.; Rüffer, T.; Lang, H. Synthesis with Perfect Atom Economy: Generation of Furan Derivatives by 1,3-Dipolar Cycloaddition of Acetylenedicarboxylates at Cyclooctynes. Molecules 2014, 19, 14022-14035

Cyclooctyne and cycloocten-5-yne undergo, at room temperature, a 1,3-dipolar cycloaddition with dialkyl acetylenedicarboxylates 1a,b to generate furan-derived short-lived intermediates 2, which can be trapped by two additional equivalents of 1a,b or

Externí odkaz: https://monarch.qucosa.de/id/qucosa%3A20123
https://monarch.qucosa.de/api/qucosa%3A20123/attachment/ATT-0/
https://monarch.qucosa.de/api/qucosa%3A20123/attachment/ATT-1/
https://monarch.qucosa.de/api/qucosa%3A20123/attachment/ATT-2/

Synthesis with perfect atom economy: generation of furan derivatives by 1,3-dipolar cycloaddition of acetylenedicarboxylates at cyclooctynes.

Autor: Banert K; Organic Chemistry, Technische Universität Chemnitz, Strasse der Nationen 62, 09111 Chemnitz, Germany. klaus.banert@chemie.tu-chemnitz.de., Bochmann S; Organic Chemistry, Technische Universität Chemnitz, Strasse der Nationen 62, 09111 Chemnitz, Germany. sandra.bochmann@chemie.tu-chemnitz.de., Ihle A; Organic Chemistry, Technische Universität Chemnitz, Strasse der Nationen 62, 09111 Chemnitz, Germany. andreas.ihle@chemie.tu-chemnitz.de., Plefka O; Organic Chemistry, Technische Universität Chemnitz, Strasse der Nationen 62, 09111 Chemnitz, Germany. oliver.plefka@web.de., Taubert F; Organic Chemistry, Technische Universität Chemnitz, Strasse der Nationen 62, 09111 Chemnitz, Germany. florian.taubert@s2008.tu-chemnitz.de., Walther T; Organic Chemistry, Technische Universität Chemnitz, Strasse der Nationen 62, 09111 Chemnitz, Germany. tina.walther@s2008.tu-chemnitz.de., Korb M; Inorganic Chemistry, Technische Universität Chemnitz, 09107 Chemnitz, Germany. marcus.korb@s2007.tu-chemnitz.de., Rüffer T; Inorganic Chemistry, Technische Universität Chemnitz, 09107 Chemnitz, Germany. tobias.rueffer@chemie.tu-chemnitz.de., Lang H; Inorganic Chemistry, Technische Universität Chemnitz, 09107 Chemnitz, Germany. heinrich.lang@chemie.tu-chemnitz.de.

Publikováno v: Molecules (Basel, Switzerland) [Molecules] 2014 Sep 05; Vol. 19 (9), pp. 14022-35. Date of Electronic Publication: 2014 Sep 05.