Zobrazeno 1 - 10
of 29
pro vyhledávání: '"Tatiana A. Stromnova"'
Autor:
Tatiana A. Stromnova, O. N. Shishilov, Judith A. K. Howard, I. A. Efimenko, Natalia A. Minaeva, Andrei V. Churakov
Publikováno v:
Journal of Organometallic Chemistry. 696:2023-2029
New palladium nitrosyl carboxylate complexes Pd8(CO)4−m(NO)m(NO2)4(RCO2)8 (m = 2, 4) were obtained by the treatment of palladium carbonyl carboxylates clusters cyclo-Pdn(μ-CO)n(μ-RCO2)n (n = 6) (1) with gaseous nitrogen monoxide. These complexes
Autor:
Roman E. Podobedov, I. A. Efimenko, Andrei V. Churakov, Tatiana A. Stromnova, Lyudmila G. Kuzmina
Publikováno v:
Journal of Organometallic Chemistry. 695:2083-2088
An interaction of Pd3(NO)2(μ-CF3CO2)4(η2-C6H5Me)2 (I) with alkenes has been studied. A replacement of η2-coordinated arene by various olefins has been found to result in complexes of different nuclearity, Pd3(NO)2(μ-CF3CO2)4(η2-L)2 (L = Me3CCH C
Autor:
Andrei V. Churakov, Tatiana A. Stromnova, O. N. Shishilov, Lyudmila G. Kuzmina, Judith A. K. Howard
Publikováno v:
Journal of Organometallic Chemistry. 694:1453-1458
The reaction of palladium carbonyl carboxylates Pd 6 (CO) 6 (RCOO) 6 with gaseous nitrogen monoxide was investigated. These clusters were found to promote the NO disproportionation into N 2 and NO 2 under mild conditions. The reaction is accompanied
Autor:
Tatiana A. Stromnova
Publikováno v:
Russian Journal of Inorganic Chemistry. 53:2019-2047
The review considers palladium carboxylate complexes containing a Pd(μ-OOCR)2Pd group, starting with dinuclear complexes and finishing with the currently largest octanuclear nitrosylcarboxylates, their structure, synthesis, and spectroscopic charact
Autor:
Tatiana A. Stromnova, O. N. Shishilov
Publikováno v:
Russian Chemical Bulletin. 57:2275-2280
The reaction of the palladium(i) cluster Pd6(CO)6(OCOCMe3)6 having a cyclic metal core with gaseous nitrogen monoxide was studied by electronic absorption spectroscopy, IR spectroscopy, and GLC. In the system studied NO acts as an oxidant for both co
Autor:
Tatiana A. Stromnova, K. Yu. Monakhov
Publikováno v:
Russian Journal of General Chemistry. 77:1896-1903
Ab initio Hartree-Fock calculations of the geometries and electronic structures of saturated (including halogen-substituted), unsaturated, and aromatic carboxylic acids and their anions were performed. Factors governing the donor-acceptor power of th
Autor:
Tatiana A. Stromnova, O. N. Shishilov, Lyudmila G. Kuzmina, I. A. Efimenko, Andrei V. Churakov
Publikováno v:
Russian Journal of Inorganic Chemistry. 51:574-580
Methods for the synthesis of new palladium(II) acetate complexes [L2Pd(OCOCH3)2], where L is N-coordinated morpholine (C4H9ON) or 4-methylmorpholine (C5H11ON), have been developed. The structure of the complex (C4H9ON)2Pd(OAc)2 · 2H2O (1) has been e
Autor:
Tatiana A. Stromnova, Mikhail V. Daineko, Lyubov’ I. Boganova, Judith A. K. Howard, Lyudmila G. Kuzmina, Sergei B. Katser, Denis V. Paschenko, Andrei V. Churakov
Publikováno v:
Inorganica Chimica Acta. 350:283-288
Two types of palladium nitrosyl carboxylate complexes were synthesized and their structures were characterized by several methods including an X-ray diffraction analysis. The tetranuclear complexes Pd4(μ-NO)2(OCOR)6 (R=CMe3, Me, Ph, CHMe2, CH2Cl, II
Autor:
Tatiana A. Stromnova, Michael N. Vargaftik, Tatiana V. Chernysheva, Ilya I. Moiseev, S. T. Orlova, Igor P. Stolarov
Publikováno v:
Catalysis Today. 51:595-602
Coordinated carbene and nitrene species were suggested as the key intermediates in hydrogen-transfer reduction of multiple bonds and reduction of nitroaromatics by CO catalysed with giant Pd-561 clusters as well as in the reaction of Pd (I) carbonyla
Publikováno v:
Organometallics. 16:2827-2832
The energies of the intense bands in the near-UV−vis spectra of a number of axially substituted Mn2(CO)8L2 and Co2(CO)6L2 complexes containing non-π-acid phosphine substituents have been measured in solution. When combined with data reported previ