Mechanistic diversity in acetophenone transfer hydrogenation catalyzed by ruthenium iminophosphonamide complexes

Autor: Rinaldo Poli, Tat'yana A. Peganova, Alexander M. Kalsin, Eric Deydier, Natalia V. Belkova, Iana S. Sinopalnikova, Ivan V. Fedyanin

Publikováno v: Dalton Transactions
Dalton Transactions, Royal Society of Chemistry, 2020, 49 (5), pp.1473-1484. ⟨10.1039/c9dt04532e⟩
Dalton Transactions, 2020, 49 (5), pp.1473-1484. ⟨10.1039/c9dt04532e⟩

International audience; A series of arene ruthenium iminophosphonamide complexes, [(Arene)RuCl{R2P(NR′)2}] (1), bearing various arenes and R,R′ substituents on the NPN ligand have been investigated as precatalysts in acetophenone transfer hydroge

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::9e3202a302227bde37707cc764f4edee
https://doi.org/10.1039/c9dt04532e

The Origin of the MNXN Metallacycle Flexibility in the Chelate Iminophosphonamide and Amidinate Transition Metal Complexes

Autor: Oleg A. Filippov, Alexander M. Kalsin, Ivan V. Fedyanin, Tat'yana A. Peganova, Natalia V. Belkova

Publikováno v: European Journal of Inorganic Chemistry. 2018:5098-5107

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::9f4bad46040b4ab2cfeac3dffb487237
https://doi.org/10.1002/ejic.201801119

Ruthenium p-cymene iminophosphonamide complexes: Activation under basic conditions and transfer hydrogenation catalysis

Autor: Rinaldo Poli, Natalia V. Belkova, Iana S. Sinopalnikova, Alexander M. Kalsin, Tat'yana A. Peganova, Eric Deydier, Jean-Claude Daran, Elena S. Shubina

Publikováno v: European Journal of Inorganic Chemistry
European Journal of Inorganic Chemistry, Wiley-VCH Verlag, 2018, 2018 (20-21), pp.2285-2299. ⟨10.1002/ejic.201701344⟩
European Journal of Inorganic Chemistry, 2018, 2018 (20-21), pp.2285-2299. ⟨10.1002/ejic.201701344⟩

International audience; Complex [(η6-Cym)RuCl(NPN)] Cym = p-cymene; NPN = (pTolN)2PPh2 (1) yields a thermally sensitive hydride derivative [(η6-Cym)RuH(NPN)] (2) by reaction with iPrOH in the presence of a strong base, via an observable isopropoxid

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::7708cafddecab3584e8201b460728795
https://hal.archives-ouvertes.fr/hal-01954087

Palladium(II) aminoiminophosphoranate complexes as cross-coupling catalysts

Autor: Andrei A. Vasil'ev, Tat'yana A. Peganova, Alexander M. Kalsin, Nikolai A. Ustynyuk

Publikováno v: Russian Chemical Bulletin. 63:2305-2308

The Tsuji-Trost reaction between diethyl malonate and allyl acetate catalyzed by palladium(II) NPN-aminoiminophosphoranate complexes yields mono- and diallylation products in the ratios depending on the complex used. The Suzuki-Miyaura cross-coupling

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::77b39c19b0eb50694372fb4273083384
https://doi.org/10.1007/s11172-014-0739-8

Synthesis of Diaminophosphonium Salts [Ph2(ArNH)2P]+Br− (Ar = o-MeC6H4, p-MeC6H4, p-Pr i C6H4, p-EtO2CC6H4, p-MeOC6H4)

Autor: K. A. Lyssenko, Nikolai A. Ustynyuk, Tat'yana A. Peganova, Pavel V. Petrovskii, A. V. Gonchar, Oleg V. Gusev

Publikováno v: Phosphorus, Sulfur, and Silicon and the Related Elements. 184:322-331

The behavior of different anilines H2NC6H4R (R = o-Me, p-Me, o-, m- and p− i Pr, p-OMe, p-CO2Et) and 2,6-Me2C6H3NH2 towards trihalophosphoranes was studied. 2,6-Me2C6H3NH2 failed to form the diaminophosphonium salt [Ph2PNH(2,6-Me2C6H3)2]Br, and the

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::2428ab9ebf00836a56f522952ba9a6f2
https://doi.org/10.1080/10426500802116073