Zobrazeno 1 - 10
of 16
pro vyhledávání: '"Tapash Deb"'
Autor:
Caitlin M. Anderson, Colin P.S. Kruse, Michael P. Jensen, Ahmed M. Aboelenen, Jeffrey L. Petersen, Tapash Deb
Publikováno v:
European Journal of Inorganic Chemistry. 2016:2474-2485
A “second-generation” scorpionate ligand was utilized to prepare the nickel(II) borohydride complex [(TpPh,Me)Ni(η3-BH4)], wherein the borohydride was coordinated through two bridging B–H bonds, leaving two terminal B–H bonds uncoordinated a
Autor:
Michael P. Jensen, Tapash Deb, Caitlin M. Anderson, Jeffrey L. Petersen, Huaibo Ma, Victor G. Young
Publikováno v:
European Journal of Inorganic Chemistry. 2015:458-467
Pseudotetrahedral scorpionato halide complexes [(TpPh,Me)Ni–X] [TpPh,Me = hydrotris(3-phenyl-5-methyl-1-pyrazolyl)borate] were synthesized by metathesis of Tl(TpPh,Me) and NiX2 (X = Cl, Br, I). Pyrazole adducts [(TpPh,Me)Ni(HpzPh,Me)(X)] (X = Cl, I
Publikováno v:
ChemInform. 47
Crystals of Na5 [NaU(Mo6P4O31H7)2] ·(H2O)n (I) are prepared by slow evaporation of an aqueous solution containing Na2MoO4, UO2(NO3)2, Na2S2O4, H3PO4 (pH 2.4 adjusted with HOAc, ≈30% yield).
Publikováno v:
Inorganic Chemistry. 51:7257-7270
Pseudotetrahedral nickel(II) phenolate complexes Tp(R,Me)Ni-OAr (Tp(R,Me) = hydrotris(3-R-5-methylpyrazol-1-yl)borate; R = Ph {1a}, Me {1b}; OAr = O-2,6-(i)Pr(2)C(6)H(3)) were synthesized as models for nickel-substituted copper amine oxidase apoenzym
Publikováno v:
Inorganic Chemistry. 49:457-467
Several derivatives of the pseudotetrahedral phenylthiolate complex Tp(Me,Me)Ni-SPh (1), Tp(Me,Me-) = hydrotris(3,5-dimethyl-1-pyrazolyl)borate, were prepared incorporating substituted arylthiolates, including a series of ortho-substituted ligands Tp
Autor:
Jeffrey L. Petersen, Victor G. Young, Tapash Deb, Michael P. Jensen, Swarup Chattopadhyay, Huaibo Ma
Publikováno v:
Inorganic Chemistry. 47:3384-3392
Five new pseudotetrahedral nickel(II) arylthiolate complexes Tp (R,Me)Ni-SR' [(Tp (R,Me)) (-) = 2,2,2-kappa (3)-hydridotris(3-R,5-methylpyrazolyl)borate; R = Me, R' = C 6H 5 (Ph), 2,4,6-C 6H 2(CH 3) 3 (Mes); R = Ph, R' = C 6H 5 (Ph), 2,4,6-C 6H 2(CH
Publikováno v:
Inorganic chemistry. 55(2)
Crystals of [NaU(Mo6P4O31H7)2]·5Na·(H2O)n (NaUMo6) have been synthesized by slow evaporation of an aqueous mixture containing uranyl nitrate, sodium molybdate, phosphoric acid, and sodium dithionate. Single crystal diffraction of NaUMo6 reveals the
Autor:
Michael P. Jensen, Tapash Deb
Publikováno v:
Inorganic chemistry. 54(1)
A kinetic study is reported for reactions of pseudotetrahedral nickel(II) arylthiolate complexes [(Tp(R,Me))Ni-SAr] (Tp(R,Me) = hydrotris{3-R-5-methyl-1-pyrazolyl}borate, R = Me, Ph, and Ar = C6H5, C6H4-4-Cl, C6H4-4-Me, C6H4-4-OMe, 2,4,6-Me3C6H2, 2,4
Autor:
Swarup Chattopadhyay, Tapash Deb, Caitlin M. Anderson, Michael P. Jensen, Victor G. Young, Huaibo Ma
Publikováno v:
Dalton transactions (Cambridge, England : 2003). 43(46)
Synthesis and characterization of several new pseudotetrahedral arylthiolate complexes [(Tp(Ph,Me))Ni-SAr] (Tp(Ph,Me) = hydrotris{3-phenyl-5-methyl-1-pyrazolyl}borate; Ar = Ph, 2,4,6-(i)Pr3C6H2, C6H4-4-Cl, C6H4-4-Me, C6H4-4-OMe) are reported, includi
Publikováno v:
Inorganic chemistry. 53(19)
Self-assembly of uranyl peroxide polyoxometalates (POMs) in alkaline peroxide solutions has been known for almost a decade, but in these dynamic solutions that contain high concentrations of base and peroxide the reaction pathway could never be disce