Zobrazeno 1 - 10
of 19
pro vyhledávání: '"Tapan Maji"'
Publikováno v:
Journal of Molecular Catalysis A: Chemical. 424:145-152
The (DIOP)rhodium-catalyzed hydroformylation of butadiene has been shown to give among the highest selectivities for formation of adipaldehyde, which is useful for the synthesis of nylon. Herein, isomerizing hydroformylation is shown to be a mechanis
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::157145747ab96e941a82832e3e76f37c
https://doi.org/10.1016/j.molcata.2016.08.021
https://doi.org/10.1016/j.molcata.2016.08.021
Publikováno v:
ChemCatChem. 8:3343-3346
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::1d4cd8ecea02fc009b284dad5f25e77a
https://doi.org/10.1002/cctc.201600654
https://doi.org/10.1002/cctc.201600654
Autor:
Jon A. Tunge, Tapan Maji
Publikováno v:
Organic Letters. 17:4766-4769
An interceptive decarboxylative allylation protocol has been developed utilizing pyrone as a C4 synthon. This palladium-catalyzed transformation difunctionalizes the pyrone moiety by in situ generation and activation of both the electrophile and nucl
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::dcd81e31011d3e4bf03c0ef8ee6555f0
https://doi.org/10.1021/acs.orglett.5b02308
https://doi.org/10.1021/acs.orglett.5b02308
Publikováno v:
Organic letters. 19(15)
A new method is developed for the synthesis of spirooxindoles from amines and isatins via C–H functionalization. The reaction leverages the tert-amino effect to form an enolate–iminium intermediate via [1,5]-hydride shift followed by cyclization.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::b9e721882517fbcbf6893d14355031a5
https://pubmed.ncbi.nlm.nih.gov/28737400
https://pubmed.ncbi.nlm.nih.gov/28737400
Autor:
Jon A. Tunge, Tapan Maji
Publikováno v:
ChemInform. 47
An interceptive decarboxylative allylation protocol has been developed utilizing pyrone as a C4 synthon. This palladium-catalyzed transformation difunctionalizes the pyrone moiety by in situ generation and activation of both the electrophile and nucl
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::ba221706d006da01d0f6294d835828d4
https://doi.org/10.1002/chin.201608076
https://doi.org/10.1002/chin.201608076
Publikováno v:
ChemInform. 46
The retro-Claisen activation is applicable to primary and secondary benzyl alcohols and hetarylmethyl alcohols.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::8b64428ee80e66e6e6d0828196feb2ea
https://doi.org/10.1002/chin.201513136
https://doi.org/10.1002/chin.201513136
Autor:
Tapan Maji, Jon A. Tunge
Publikováno v:
ChemInform. 46
The method utilizes an aldehyde to activate nitriles toward α-allylation and prevent multiple allylations.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::90c29214590033b6b20c587b2cfd83c0
https://doi.org/10.1002/chin.201513115
https://doi.org/10.1002/chin.201513115
Publikováno v:
Tetrahedron. 62:8959-8965
Chloramphenicol and thiamphenicol have been enantioselectively synthesized using an asymmetric halohydrin reaction as a key step. In particular, halomethoxylation reaction was used, where O-methyl functions as a hydroxyl protecting group and eliminat
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::fe80bf9af7233298ce3d34a3753b97f2
https://doi.org/10.1016/j.tet.2006.07.014
https://doi.org/10.1016/j.tet.2006.07.014
Publikováno v:
Chemical communications (Cambridge, England). 50(90)
A new strategy has been developed for the benzylation of nitriles directly from benzyl alcohols. In this process benzyl alcohols undergo retro-Claisen activation with cyanoacetic esters to generate an active electrophile and a carbanionic nucleophile
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::5fd6e3a785a6547a9964bf286d8b706f
https://pubmed.ncbi.nlm.nih.gov/25269424
https://pubmed.ncbi.nlm.nih.gov/25269424
Autor:
Tapan Maji, Jon A. Tunge
Publikováno v:
Organic letters. 16(19)
α-Cyano aldehydes undergo selective transition-metal-catalyzed monoallylation to provide α-allylated nitriles. The transformation leads to linear substitution products with palladium catalysts or branched allylated nitriles using an iridium catalys
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::3af4ec01ec958e99419f50826addcf46
https://pubmed.ncbi.nlm.nih.gov/25238334
https://pubmed.ncbi.nlm.nih.gov/25238334