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pro vyhledávání: '"Tanno Schmidt"'
Publikováno v:
Chemistry (Weinheim an Der Bergstrasse, Germany)
Herein, we describe the acid/Pd‐tandem‐catalyzed transformation of glycol derivatives into terminal formic esters. Mechanistic investigations show that the substrate undergoes rearrangement to an aldehyde under [1,2] hydrogen migration and cleava
Publikováno v:
Organic Letters. 21:50-55
A general and efficient Ni-catalyzed coupling of challenging aryl chlorides and in situ generated aliphatic and aromatic thiolates is described. The employed on-cycle, air-stable defined Ni precatalysts allow for transformation of a broad scope of su