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pro vyhledávání: '"Tanja Seraidaris"'
Publikováno v:
Dalton Trans.. :2098-2105
Among the 2-substituted indenes, 2-trifluoroindene and 2-tert-butylindene are poorly or incompletely described in the open literature. We herein describe an efficient one-pot synthesis of these compounds as a variation of the Perkin reaction which al
Publikováno v:
Polymer. 47:107-112
Propene homopolymers and propene–ethene copolymers with small amount of ethene were synthesized using three catalyst systems [p-CH3OPh2C(2,7-di-tertBuFlu)(Cp)]ZrCl2/Me2HNPh][B(C6F5)4] (Cat I), [p-CH3OPh2C(2,7-di-tertBuFlu)(Cp)]ZrCl2/[Ph3C][B(C6F5)4
Autor:
Jukka Seppälä, Markku Leskelä, Timo Repo, Mikko Karesoja, Arto Puranen, Tanja Seraidaris, Barbro Löfgren
Publikováno v:
Journal of Polymer Science Part A: Polymer Chemistry. 44:4743-4751
Elastic polypropene has gained growing industrial and academic interest as a thermoplastic elastomer. In this study, "rac"- and "meso"-dimethylsilyl(3-benzylindenyl)(2-methylindenyl)hafnium dichloride complexes (Hfr and Hfm, respectively), activated
Publikováno v:
Macromolecular Chemistry and Physics. 206:1319-1325
Propene-ethene copolymers with low to moderate amounts of ethene were synthesised with two C s -symmetric metallocene complexes, [(p-CH 3 OPh)2C(2,7-di- t BuFlu)-(Cp)]ZrCl 2 (I) and [(p-CH 3 OPh)2C(2,7-di- t BuFlu)(Cp)]HfCl2 (Ia). Methylalumoxane (MA
Autor:
Tanja Seraidaris, Ole Swang, Richard H. Heyn, Carl-Henrik Görbitz, Richard Blom, Andreas Möller
Publikováno v:
European Journal of Inorganic Chemistry. 2005:1759-1769
The systematic synthesis of 1,3-dialkyl-substituted 2-silylindenes and their suitability as zirconocene ligands is discussed. Unexpected reactivities rendered a number of substitution patterns unfeasible, especially for alkyl groups other than methyl
Publikováno v:
Journal of Polymer Science Part A: Polymer Chemistry. 43:6455-6464
The activity of metallocene/methylaluminumoxane (MAO) catalysts in olefin polymerization is highly dependent on both the alkylation and activation of the complexes. The leaving ligands have an important role in the complex activation, influencing the
Publikováno v:
Macromolecular Chemistry and Physics. 205:1064-1069
Propene polymerisation was conducted with three ansa-zirconocene complexed: Me 2 Si(2-Me-4-PhInd) 2 -Zrcl 2 (A), Me 2 Si(2-Me-4-PhInd) 2 ZrClNMe 2 (B) and Me 2 Si-(2-Me-4-PhInd) 2 ZrClNEt 2 (C). Methylalumoxane (MAO) or [HNPhMe 2 ][B(C 6 F 5 ) 4 ] wa
Publikováno v:
Macromolecular Chemistry & Physics; Jul2005, Vol. 206 Issue 13, p1319-1325, 7p
Autor:
Andreas C. Mller, Richard Blom, Richard H. Heyn, Ole Swang, Carl-Henrik Grbitz, Tanja Seraidaris
Publikováno v:
European Journal of Inorganic Chemistry; May2005, Vol. 2005 Issue 9, p1759-1769, 11p
Publikováno v:
Macromolecular Chemistry & Physics; May2004, Vol. 205 Issue 8, p1064-1069, 6p