Zobrazeno 1 - 10
of 19
pro vyhledávání: '"Tanasri Bunlaksananusorn"'
Autor:
Tanasri Bunlaksananusorn, Eberhardt Herdtweck, Florian Rampf, Lars Rodefeld, Wolfgang A. Herrmann, Stephan D. Hoffmann, Denys Baskakov
Publikováno v:
Organometallics. 25:2449-2456
New and reliable procedures for the preparation of both enantiomers of 2,2‘-bipiperidine have been developed. Chiral imidazolinium salts derived from 2,2‘-bipiperidine and partially reduced biisoquinoline were prepared in high yields. Rhodium and
Publikováno v:
Synlett. :2240-2242
Ir-catalyzed asymmetric hydroboration of bicyclic hydrazine 4 in the presence of chiral ligand la, leads to bicyclic alcohol 5 after oxidative workup in good yield (76%) and moderate enantioselectivity (71 % ee).
Autor:
Paul Knochel, Tanasri Bunlaksananusorn
Publikováno v:
Tetrahedron Letters. 43:5817-5819
The use of t -BuOK in DMSO allows a smooth addition of Ph 2 PH, Cy 2 PH and Ph 2 P(O)H to various functionalized alkenes leading to polyfunctional phosphines in good yields. This method has been used to prepare precursors for P,P- and P,N-ligands.
Publikováno v:
ChemInform. 31
A convenient and general synthetic method for spiro[4.n]alk-2-ene-1,6-diones and spiro[5.n]alk-2-ene-1,7-diones, which involves the intramolecular acylation of an α-sulfinyl carbanion, is described.
Autor:
Paul Knochel, Jesús A. Varela, Lars O. Bromm, Andreas Boudier, Frederic Lhermitte, Christopher Koradin, Alain Louis Rodriguez, Tanasri Bunlaksananusorn, Hamid Laaziri, Eike Hupe
Publikováno v:
ChemInform. 32
Main-group organometallics are useful intermediates for the chemoselective and diastereoselective C-C bond formation. The boron-zinc exchange is a unique way for preparing chiral secondary alkylzinc reagents which are configurationally stable over a
Publikováno v:
ChemInform. 32
Catalytic amounts of t-BuOK in DMSO allow the smooth addition of nitriles and in some cases of ketones to vinylsilanes, phosphines or thio derivatives in good yields.
Autor:
Tanasri Bunlaksananusorn, Paul Knochel
Publikováno v:
ChemInform. 33
The use of t -BuOK in DMSO allows a smooth addition of Ph 2 PH, Cy 2 PH and Ph 2 P(O)H to various functionalized alkenes leading to polyfunctional phosphines in good yields. This method has been used to prepare precursors for P,P- and P,N-ligands.
Publikováno v:
ChemInform. 38
Reaction of nitrones with terminal alkynes occurs in the presence of 1 equiv of trimethylaluminum and leads to the corresponding propargylic hydroxylamines in yields ranging from 49 to 90%.
Publikováno v:
ChemInform. 37
We report a facile one-pot synthesis of chiral β-amino esters via direct reductive amination of (3-keto esters with ammonium acetate (NH 4 OAC) and H 2 in the presence of chiral Ru-ClMeOBIPHEP catalysts using 2,'2,2-trifluoroethanol (TFE) as a solve
Autor:
Tanasri Bunlaksananusorn, Paul Knochel
Publikováno v:
The Journal of organic chemistry. 69(14)
A novel synthesis of effective chiral P,N- and P,P-ligands has been developed by using a t-BuOK-mediated hydrophosphination of chiral alkenylpyridines and alkenylphosphine oxides. Ir complexes of chiral P,N-ligands 1 and 3 gave high enantioselectivit