Zobrazeno 1 - 10
of 347
pro vyhledávání: '"Tamotsu Fujisawa"'
Autor:
Kazumasa Shindo, Yoshito Yamamoto, Tamotsu Fujisawa, Yasuko Togamura, Takeshi Shibuya, Yoshiro Tozawa, Seiji Nakao, Kiyoshi Hirano, Hirotake Miyaji, Hideto Mashiyama, Michinaga Nakamura
Publikováno v:
Grassland Science.
Radioactive cesium (Cs) concentration of vegetation and soil was monitored in grasslands in seven farms located at a distance ranging from 90 to 180 km from the Fukushima nuclear power plant during seven months following the reactor meltdown in March
Publikováno v:
Tetrahedron Letters. 40:1953-1956
The bakers' yeast reduction of trifluoroacetyl derivatives was examined in the presence of various esters of methanethiosulfonate. The yeast reduction of 4-bromo-4′-trifluoroacetylbiphenyl using the cyclohexylmethyl methanethiosulfonate resulted in
Publikováno v:
Tetrahedron Letters. 39:9735-9738
A novel alkylating ring cleavage reaction of enantiomerically pure β-trichloromethyl-β-propiolactone as a chiral building block with organoaluminum compounds provided ring-opened products with a chiral trichloromethyl carbinol moiety. A product was
Publikováno v:
Tetrahedron Letters. 39:6019-6022
The reduction of (trifluoroacetyl)biphenyl derivatives with catecholborane as a stoichiometric reductant in the presence of the oxazaborolidine catalyst derived from L-threonine in dichloromethane-toluene at −90 °C proceeds to give the correspondi
Publikováno v:
Tetrahedron. 54:10265-10274
Highly enantioselective reduction of 1,2-diaryl-2-benzyloxyiminoethanones and 1,2-diarylethanediones was conducted using oxazaborolidine derived from L-threonine and borane complexes to give β-imino alcohols and 1,2-diaryl-1,2-ethanediols in high en
Publikováno v:
Tetrahedron. 54:8393-8402
The reduction of trifluoromethyl ketones containing a sulfur functionality by the crude alcohol dehydrogenase from Geotrichum proceeded successfully, and the corresponding optically active alcohols were synthesized with high yields and excellent enan
Publikováno v:
Tetrahedron. 54:5523-5530
Novel chiral fluorinated building block, (S)β-chlorodifluoromethyl-β-propiolactone with up to >99% ee was prepared using the Lewis acid catalyzed [2+2]cycloaddition of ketene with chlorodifluoroacetaldehyde followed by enzymatic resolution with a l
Publikováno v:
Tetrahedron. 54:4267-4276
The bakers' yeast reduction of (trifluoroacetyl)biphenyl derivatives produces (R)-trifluoromethyl biphenylyl carbinols in high enantioselectivity, whereas the reduction of the same derivatives with Geotrichum candidum acetone powder gives the corresp
Autor:
Tamotsu Fujisawa, Makoto Shimizu
Publikováno v:
Journal of Synthetic Organic Chemistry, Japan. 56:672-680
Widespread use of homochiral 1, 2-diary1-1, 2-diaminoethanes and 2-amino-1, 2-diarylethanols as chiral auxiliaries coupled with difficulties associated with their preparation prompted us to investigate new methodologies for their syntheses. For the p
Publikováno v:
Tetrahedron Letters. 39:67-70
Improvement of the enantioselectivity and enhancement of the reactivity were achieved in the bakers' yeast reduction of the β-keto ester derivatives by the addition of a sulfur compound. © 1997 Elsevier Science Ltd. All rights reserved.