Zobrazeno 1 - 6
of 6
pro vyhledávání: '"Takenori Omata"'
Publikováno v:
Heteroatom Chemistry. 13:351-356
The reaction of 3,8-bis(diazo)-2,2,4,4,7,7,9,9-octamethyldecane (5) with elemental selenium in 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) at 130°C yielded 1,2-di-tert-butyl-3,3,6,6-tetramethylcyclohexene (1) (64%) and trans-3,8-di-tert-butyl-4,4,7,7-t
Publikováno v:
Bulletin of the Chemical Society of Japan. 73:729-737
2,2,4,4-Tetramethyl-1-phenyl-6,7-dithiabicyclo[3.1.1]heptane was treated with 2KHSO5·KHSO4·K2SO4 to yield cis- and trans-3,6-bis(1,1,3,3-tetramethyl-4-oxo-4-phenylbutyl)-1,2,4,5-tetrathianes. The formation mechanism of the tetrathianes is discussed
Autor:
Chie Tsuchiya, Takahiro Shimada, Akihiko Ishii, Ken Furusawa, Juzo Nakayama, and Takenori Omata
Publikováno v:
The Journal of Organic Chemistry. 65:1799-1806
Two sterically congested cycloalkenes (9 and 10), congeners of tetra-tert-butylethylene, were synthesized and characterized. Oxidation of the bicyclic 1,3-dithietane 8 with dimethyldioxirane (DMD) gave the endo,endo-disulfoxide 13, thermal isomerizat
Publikováno v:
ChemInform. 31
2,2,4,4-Tetramethyl-1-phenyl-6,7-dithiabicyclo[3.1.1]heptane was treated with 2KHSO5·KHSO4·K2SO4 to yield cis- and trans-3,6-bis(1,1,3,3-tetramethyl-4-oxo-4-phenylbutyl)-1,2,4,5-tetrathianes. The formation mechanism of the tetrathianes is discussed
Publikováno v:
ChemInform. 31
Publikováno v:
ChemInform. 33
The reaction of 3,8-bis(diazo)-2,2,4,4,7,7,9,9-octamethyldecane (5) with elemental selenium in 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) at 130°C yielded 1,2-di-tert-butyl-3,3,6,6-tetramethylcyclohexene (1) (64%) and trans-3,8-di-tert-butyl-4,4,7,7-t