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pro vyhledávání: '"Takatoshi Nakahira"'
Publikováno v:
ChemInform. 23
Publikováno v:
Journal of Molecular Catalysis. 74:489-498
Terminal alkenes such as 1-decene were oxygenated to methyl ketones under atmospheric pressure of O2, when a catalyst system of PdCl2(MeCN)2, CuCl and HMPA was used in anhydrous 1,2-dichloroethane. With this catalyst system, silyl enol ethers can be
Autor:
Shunji Aoki, Yoshinori Yoshida, Minoru Takano, Takatoshi Nakahira, Takahiro Hosokawa, Shun-Ichi Murahashi
Publikováno v:
J. Chem. Soc., Chem. Commun.. :1559-1560
Treatment of N-allylamides 1a–c and lactams 1d–f with molecular oxygen in the presence of [PdCl2(MeCN)2]–CuCl catalyst in anhydrous 1,2-dichloroethane containing hexamethylphosphoric triamide gives the corresponding aldehydes 2 regioselectively