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Autor:
Eiko Ohata, Takako Iseki, Tatsuo Fujino, Satoshi Maeda, Seiki Saito, Toshiaki Aikawa, Teruhiko Ishikawa, Takashi Matsuo
Publikováno v:
ChemInform. 38
Enolate generated from O-(tetrahydropyran-2-yl)hydroxyacetone under thermodynamically controlled conditions (1.3 equiv of NaH, THF, 0 degrees C to rt) was allylated at the carbon bearing the protected hydroxy group with very high regioselectively. Wh