Zobrazeno 1 - 8
of 8
pro vyhledávání: '"Takaki Kurosawa"'
Publikováno v:
Organometallics. 37:1892-1899
The chiral-at-metal complexes (RFe,RC)/(SFe,RC)-[CpFe(Prophos)NCR]X (X = I, PF6; R = Et, Ph, p-substituted Ph) were prepared, and the diastereomers were separated by fractional crystallization. Eight diastereomerically pure complexes (SFe,RC)-[CpFe(P
Autor:
Henri Brunner, Takashi Tsuno, Michael Bodensteiner, Stefanie Gärtner, Chiemi Miyahara, Seera Ito, Takaki Kurosawa, Kazuhiro Koyama
Publikováno v:
European Journal of Inorganic Chemistry. 2016:5405-5410
Diastereomer separation by fractional crystallization is the most important method for the resolution of enantiomers in research as well as in industry. Herein we describe two different types of diastereomer co-crystallization, which impede diastereo
Autor:
Takashi Tsuno, Michael Bodensteiner, Gábor Balázs, Takaki Kurosawa, Henri Brunner, Manfred Muschiol
Publikováno v:
Organometallics. 32:4904-4911
The compounds (RFe,RC)-/(SFe,RC)-[CpFe(Prophos)PPh(OMe)2]PF6 and (RFe,RC)-/(SFe,RC)-[CpFe(Prophos)PPh2(OR)]PF6 (R = Me, Et, iPr, tBu) were synthesized, starting from (RFe,RC)-/(SFe,RC)-[CpFe(Prophos)NCMe]PF6, and characterized, including X-ray analys
Publikováno v:
Organometallics. 31:3395-3401
The compounds (RFe,RC)-/(SFe,RC)-[CpFe(Prophos)NCMe]X (X = I, PF6), configurationally labile at the metal center, were used in the MeCN/ligand exchange reactions with cyclohexyl isocyanide (CyNC) and tert-butyl isocyanide (tBuNC). Kinetic measurement
Publikováno v:
Angewandte Chemie. 124:1092-1095
Autor:
Henri Brunner, Manfred Muschiol, Manfred Zabel, Hayato Ike, Kazuhiro Koyama, Takaki Kurosawa, Takashi Tsuno
Publikováno v:
Organometallics. 30:3666-3676
The diastereomers (RFe,RC)/(SFe,RC)-[CpFe(Prophos)NCMe]X (X = I, PF6), 5:95, differing only in the metal configuration, were prepared from (RFe,RC)/(SFe,RC)-[CpFe(Prophos)I] (95:5) in acetonitrile ...
Autor:
Stefanie Gärtner, Takaki Kurosawa, Michael Bodensteiner, Seera Ito, Chiemi Miyahara, Henri Brunner, Takashi Tsuno, Kazuhiro Koyama
Publikováno v:
European Journal of Inorganic Chemistry. 2016:5399-5399
Publikováno v:
Angewandte Chemie (International ed. in English). 51(4)