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pro vyhledávání: '"Takaki Fukuoka"'
Publikováno v:
Organic letters. 22(11)
Norcorrole is a ring-contracted porphyrinoid, exhibiting distinct antiaromaticity. Herein, we report the reactions of meso-dimesitylnorcorrole Ni(II) complex with two types of carbenes: dichlorocar...
Autor:
Hisao Nishiyama, Siti Rokiah Binti Mat Napi, Jun-ichi Ito, Hajime Kameo, Takahiro Ishihara, Takaki Fukuoka
Publikováno v:
Chemical communications (Cambridge, England). 55(85)
A chirality switch between novel NCN pincer Rh complexes and a related double cyclometalated NCNC Rh complex containing secondary amino groups is described. Their catalytic abilities were determined in asymmetric alkynylation of ethyl trifluoropyruva
Autor:
Satoru Hiroto, Ko Furukawa, Takeaki Iwamoto, Shintaro Ishida, Hiroshi Shinokubo, Takaki Fukuoka, Uchida Kenya, Jong Min Lim, Ji-Young Shin, Dongho Kim, Young Mo Sung
Publikováno v:
Angewandte Chemie International Edition. 53:1506-1509
The treatment of an antiaromatic norcorrole Ni(II) complex with a kinetically stabilized silylene provided ring-expansion products in excellent yields through the highly regio- and stereoselective insertion into the β-β pyrrolic CC bonds. The re