Zobrazeno 1 - 10
of 225
pro vyhledávání: '"Takafumi, Kitazawa"'
Publikováno v:
Dalton Transactions. 52:2571-2579
We synthesized novel “Soma–Iwamoto-type” complexes that contain the 4-methoxypyrimidine ligand. The guest clathrate complexes demonstrate the SCO phenomenon and interesting rarely reported penetrated structures with two Soma–Iwamoto-type stru
Autor:
Takafumi Kitazawa, Yoichi Ikeda, Yusei Shimizu, Akira Matsuo, Minoru Yamashita, Koichi Kindo, Masaki Fujita
Publikováno v:
Proceedings of the 29th International Conference on Low Temperature Physics (LT29).
Publikováno v:
Croatica Chemica Acta, Vol 89, Iss 1, Pp 111-115 (2016)
57Fe Mössbauer spectroscopic results on the 2D Hofmann-like coordination polymer Fe(4-Clpy)2Ni(CN)4 (sample 1) indicate that iron(II) ions are in a high spin state both at R.T. and T = 80 K, showing that the compound exhibits no spin crossover (SCO)
Externí odkaz:
https://doaj.org/article/85741c4811894145835b57107ab35740
Autor:
Yoichi Ikeda, Yoshihiko Umemoto, Daiju Matsumura, Takuya Tsuji, Yuki Hashimoto, Takafumi Kitazawa, Masaki Fujita
Publikováno v:
Materials Transactions; 2023, Vol. 64 Issue 9, p2254-2260, 7p
Autor:
Takafumi Kitazawa
Publikováno v:
Crystals, Vol 9, Iss 8, p 382 (2019)
The spin crossover (SCO) between multi-stable states in transition metal material is one of the attractive molecular switching phenomena which is responsive to various external stimuli such as temperature, pressure, light, electromagnetic field, radi
Externí odkaz:
https://doaj.org/article/7e267f701da749ffac29ac3cc242d6fb
Autor:
Takashi Kosone, Yoshinori Makido, Syogo Okuda, Ayaka Haigo, Takeshi Kawasaki, Daisuke Akahoshi, Toshiaki Saito, Takafumi Kitazawa
Publikováno v:
Crystals, Vol 9, Iss 7, p 370 (2019)
The synthesis, crystal structures, and magnetic properties of a new two-dimensional (2D) Hofmann-like series, FeII(L)2[AgI(CN)2]2 (L = 3-cyano-4-methylpyridine (1), allyl isonicotinate (2), phenyl-isonicotinate (3), and benzyl nicotinate (4)) were st
Externí odkaz:
https://doaj.org/article/234ebaf477844da8b8cb49d4f4f75542
Autor:
José Alberto Rodríguez-Velamazán, Kosuke Kitase, Elías Palacios, Miguel Castro, Ángel Fernández-Blanco, Ramón Burriel, Takafumi Kitazawa
Publikováno v:
Crystals, Vol 9, Iss 6, p 316 (2019)
The crystal structure of the polymeric spin crossover compound Fe(3,4-dimethyl-pyridine)2[Ag(CN)2]2 has been solved and its temperature dependence followed by means of single-crystal and powder X-ray diffraction. This compound presents a two-step spi
Externí odkaz:
https://doaj.org/article/bea6a3a33d7c4b508970b69915390c1d
Publikováno v:
Inorganic Chemistry. 60:4717-4722
The spin-crossover (SCO) phenomenon is an active area of research. This paper describes the synthesis of an Fe-Ag Hofmann-type complex, {Fe(4-methylpyrimidine)2[Ag(CN)2]2}, which demonstrates a one-step SCO and single-layer Hofmann-type structure wit
Autor:
Takeshi Kawasaki, Takafumi Kitazawa
Publikováno v:
Acta Crystallographica Section E: Crystallographic Communications, Vol 71, Iss 1, Pp 42-44 (2015)
In the title compound, [UO2(C5H7O2)2(C14H15N)], the uranyl(VI) unit ([O=U=O]2+) is coordinated to two acetylacetonate (acac) anions and one 1-phenyl-3-(pyridin-4-yl)propane (ppp) molecule. The geometry around the U atom is UNO6 pentagonal–bipyramid
Externí odkaz:
https://doaj.org/article/cb40d7d9fd954472b4555ed27cbab802
Autor:
Kosuke Kitase, Takafumi Kitazawa
Publikováno v:
Dalton Transactions. 49:12210-12214
A Hofmann-type two-step spin-crossover (SCO) complex with a pyrimidine derivative ligand, Fe(4-methylpyrimidine)2[Au(CN)2]2, was synthesized, and this complex shows a two-step SCO phenomenon in the intermediate state. Symmetry breaking also occurs in