Zobrazeno 1 - 9
of 9
pro vyhledávání: '"Taizo Hayashida"'
Publikováno v:
Microfluidics, BioMEMS, and Medical Microsystems XIV.
Based on the world-first 3D gel printing technology, we aim to develop 3D gel printing system to realize free-shape design of soft and wet materials. We defined ‘Designable Gels’ as revolutionary gels whose molecular structure, shape, and functio
Autor:
Jun ichi Terasawa, Karl Kirchner, Hideo Kondo, Yusuke Sunada, Taizo Hayashida, Hideo Nagashima
Publikováno v:
Journal of Organometallic Chemistry. 692:382-394
Triflate complexes of mono- and diruthenium amidinates, (η6-C6R6)Ru(κ1-OTf){η2-R′N C(R′′)NR′} (1: R = Me; 2: R = H) and (η5-C5Me5)Ru(μ-η2-iPrN C(Me)NiPr)Ru(κ1-OTf)(η5-C5R5) (3: R = Me; 4: R = H), are synthesized, and coordination beha
Chemistry of coordinatively unsaturated organoruthenium amidinates as entry to homogeneous catalysis
Autor:
Mitsuru Gondo, Hideo Kondo, Kazuma Miyazaki, Satoshi Masuda, Karl Kirchner, Yoshitaka Yamaguchi, Kouki Matsubara, Hideo Nagashima, Taizo Hayashida
Publikováno v:
Coordination Chemistry Reviews. 245:177-190
The chemistry of coordinatively unsaturated organoruthenium complexes is reviewed in this article. In particular, the subject is focused on neutral and cationic organoruthenium amidinates, which formally have 16 valence electrons and show signs of co
Autor:
Taizo Hayashida, Hideo Nagashima
Publikováno v:
Organometallics. 21:3884-3888
Novel ruthenium−amidinate complexes, (η6-C6H5R)Ru(η2-amidinate)X (R = Me, OMe, F) (4) and [Ru(η2-amidinate)(MeCN)4]+PF6- (5) are synthesized by photochemical displacement of the benzene ligand in (η6-C6H6)Ru(η2-amidinate)X (3) by arenes or MeC
Publikováno v:
Journal of Organometallic Chemistry. 634:167-176
A series of novel ruthenium amidinate complexes bearing η4-cyclooctadiene (COD) or η4-norbornadiene (NBD) ligand was prepared, and their structures were elucidated by spectroscopy and crystallography. A disilver amidinate, Ag2{μ2,η-PhNC(H)NPh}
Autor:
Taizo Hayashida, Hideo Nagashima
Publikováno v:
Organometallics. 20:4996-4998
Reactions of the coordinatively unsaturated complexes [(η6-C6Me6)Ru{η-iPrNC(Me)NiPr}]+X- with Me3SiCHN2 resulted in the formation of the amidinato−carbene complexes in which a trimethylsilyl group is bonded to the ruthenium atom. Migration of the
The new catalytic systems other than the Pd/Cu system have been examined for the acetic acid synthesis from methane and CO. It is found that the VO(acac) 2 /K 2 S 2 O 8 /CF 3 COOH catalyst system converts methane and CO to acetic acid in 93% yield ba
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::0748e2dfda77519f483cfd1773536dcc
https://doi.org/10.1016/s0167-2991(98)80456-4
https://doi.org/10.1016/s0167-2991(98)80456-4
Publikováno v:
Chemistry Letters. 30:954-955
The coordinatively unsaturated ruthenium(II) complexes [Ru(η6-C6R6)(η-amidinate)]+X− (R = H, Me, X = TFPB, PF6), being isoelectronic with Ru(η5-C5Me5)(η-amidinate), have been isolated and characterized by spectroscopy and crystallography. A wea
Autor:
Taizo Hayashida1, Hideo Kondo1, Jun-ichi Terasawa1, Karl Kirchner2, Yusuke Sunada1,3, Hideo Nagashima1,3 nagasima@cm.kyushu-u.ac.jp
Publikováno v:
Journal of Organometallic Chemistry. Jan2007, Vol. 692 Issue 1-3, p382-394. 13p.