Zobrazeno 1 - 10
of 55
pro vyhledávání: '"THOMAS L. NETZEL"'
Publikováno v:
Synthetic Communications. 39:4230-4238
Anthraquinone (AQ) derivatives, including members of the anthraquinone imide (AQI) family, have been synthesized to afford good candidates for electron-transfer studies in DNA. Electron-withdrawing groups on the AQ ring give a less negative reduction
Autor:
Yasser H. A. Hussein, Ibrahim M. Abdou, Thomas L. Netzel, Lucjan Strekowski, Neil A. Anderson, Morteza M. Vaghefi, Tianquan Lian, Victor A. Timoshchuk
Publikováno v:
The Journal of Physical Chemistry A. 110:4320-4328
The goal of this work is to produce high yields of long-lived AQ(*-)/dA(*+) charge transfer (CT) excited states (or photoproducts). This goal fits within a larger context of trying generally to produce high yields of long-lived CT excited states with
Publikováno v:
The Journal of Physical Chemistry B. 109:5927-5934
In this work nine DNA hairpins (HPs) are studied at room temperature to observe their pyrene(*+)/dU(*-) CT excited-state dynamics following photoexcitation at 355 nm with a 25 ps laser pulse. The HPs are 18-24 bases long, have a central tetra-T loop,
Autor:
Thomas L. Netzel, Samir T. Gaballah
Publikováno v:
Nucleosides, Nucleotides and Nucleic Acids. 21:681-694
The desire to produce reversible electron traps for direct, room temperature studies of excess electron transport in DNA duplexes and hairpins motivated our efforts first to link pyridines to 2′-deoxyuridine (pyridinyl-dU) and then to convert these
Publikováno v:
Nucleosides, Nucleotides and Nucleic Acids. 21:547-560
The synthesis of 2,2′-bipyridinyl-2′-deoxyuridine metal-chelator nucleosides (Bipy-dU) with either ethynyl or ethylenyl linkers was now been accomplished. These new nucleosides will permit the construction of a number of corresponding metallo-DNA
Autor:
Thomas L. Netzel, Charles E. Kerr, C. Denise Mitchell, Bruce E. Eaton,§ and, Yun-Ming Ying,†,‡
Publikováno v:
The Journal of Physical Chemistry B. 104:2166-2175
This paper presents results of the synthesis and photophysical study of N-(1-pyrenylmethyl)-2‘-deoxyuridine-5-carboxamide (PMA-dU) and its spectroscopic model N-acetyl-1-aminomethylpyrene (PMA-Ac). The goal in these studies is to learn about the in
Publikováno v:
The Journal of Physical Chemistry B. 104:1637-1650
This paper reports results of the synthesis and photophysical study of 5-(N-carboxy-1-aminopyrenyl)-2‘-deoxyuridine (PA-dU) and its spectroscopic model N-acetyl-1-aminopyrene (PA-Ac). Absorbance and emission spectra, emission quantum yields, and em
Autor:
Thomas L. Netzel
Publikováno v:
JBIC Journal of Biological Inorganic Chemistry. 3:210-214
This commentary article presents an overview of recent experimental results on DNA-mediated electron transfer (ET) from the perspective of semiclassical ET theory. The question concerning whether or not DNA can act as a wire is addressed. Much of the
Publikováno v:
The Journal of Physical Chemistry. 99:17936-17947
This paper reports fluorescence quantum yield, emission enhancement, and emission lifetime measurements for 10 cyanine dyes complexed to calf thymus DNA (CT-DNA), (dAdT){sub 10}, and (dGdC){sub 6} duplexes. Six of the dyes are linked bichromophores w
Publikováno v:
The Journal of Physical Chemistry. 99:17948-17955