Zobrazeno 1 - 10
of 89
pro vyhledávání: '"T.P. Stepanova"'
Publikováno v:
Polymer Science U.S.S.R.. 20:2475-2480
A study has been made of dipole polarization and of dipole moments in solutions of poly(methyl methacrylate) fractions in the thermodynamically poor solvent isopropylbenzene. It is shown that the relaxation time of the small scale process and the dip
Publikováno v:
Polymer Science U.S.S.R.. 24:1248-1253
Comparative study was made of parameters of molecular mobility of two series of “comb-like” polymers; cholesteryl esters of poly-N-methacrylyl-ω-aminocarboxylic acids and of poly-ω-methacrylyloxycarboxylic acids. It was established that the hyd
Publikováno v:
Polymer Science U.S.S.R.. 26:2897-2903
A study has been made of the gel points of comb like polymers relative to the chemical structures of their side chains, using a dielectric method to determine gel points. It was found that any modification of the structure of site chains leading to i
Publikováno v:
Polymer Science U.S.S.R.. 19:330-336
The dielectric polarization and dipole moments of gels formed by comb-like polymers have been investigated. It is shown that the macroscopic formation of a gel is proceeded by a conformational transition at the intramolecular level in the solution, w
Autor:
A.V. Kharitonov, Ya.S. Freidzon, T.P. Stepanova, T.I. Borisova, L.L. Burshtein, V.P. Shibayev
Publikováno v:
Polymer Science U.S.S.R.. 24:1664-1670
The molecular mobility in dilute solutions of esters of poly-ω-methacryloyloxycarboxylic acids has been investigated. Two relaxation processes involving dipole polarization have been observed in these systems. It has been shown that the process conn
Publikováno v:
Polymer Science U.S.S.R.. 20:1555-1560
A study was made of dielectric polarization in dilute copolymer solutions of cholesterol ester of N-methacryloyl-ω-aminolauric acid with n-butylmethacrylate and n-decylmethacrylate and homopolymers. It was shown that conformation properties and intr
Publikováno v:
Polymer Science U.S.S.R.. 17:1017-1021
Dipole polarization of poly-β-naphthyl methacrylate was studied under critical and pre-critical conditions. It was shown that when T = Tcr the molecular mobility of lateral polar groups and intramolecular interaction change.
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 28:2057-2061
1. The homologous series of β-(n-alkyldimethylsilyl)propionic acids R(CH3)2SiCH2CH2COOH (R=CH3 to C6H13) and the intermediate compounds, viz., the alkyldimethylchloromethylsilanes and alkyldimethylsilylmethylmalonates, have been synthesized. The dip
Publikováno v:
Polymer Science U.S.S.R.. 28:1150-1154
The dipole moments of of poly-ω-2-methylpropionyloxyundecyl cyanodiphenyl ester have been studied. The macromolecules of polymer have been shown to have a random coil conformation with antiparallel disposition of the cyanodiphenyl groups. The introd
Publikováno v:
Polymer Science U.S.S.R.. 24:873-877
The relaxation of the dipole polarization has been studied on dilute and concentrated solutions of 3-block copolymers, namely styrene-methyl methacrylate-styrene (ST-MMA-ST), in good and selective solvents. The kinetics depend on aggregation and stru