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Akademický článek
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Publikováno v:
ChemInform. 22
It is only since 1985 that the absolute rate constanss have been measured for some reactions of divalent silylene species. In this article the absolute rate constant data reported to date for the reactions of SiH2, SiMe2, SiMePh, SiHCl, SiCl2, SiF2 a
Publikováno v:
Research on Chemical Intermediates. 14:105-131
It is only since 1985 that the absolute rate constanss have been measured for some reactions of divalent silylene species. In this article the absolute rate constant data reported to date for the reactions of SiH2, SiMe2, SiMePh, SiHCl, SiCl2, SiF2 a
Publikováno v:
Research on Chemical Intermediates. 13:43-52
Following the newly-discovered UV absorption spectrum of Br2Si, its reactions with oxygen and nitric oxide in the gas phase have been quantitatively investigated using the flash photolysis-kinetic absorption spectroscopy technique. The room temperatu
Akademický článek
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Publikováno v:
Chemical Physics Letters. 43:130-134
Absolute rate parameters were measured for the gas phase reactions of CBr( ∼ X 2 Π) produced in the flash photolysis of CHBr 3 with a variety of paraffins, olefins, O 2 and NO. The rate of cycloaddition to unsaturated bond increases with alkyl sub
Publikováno v:
Research on Chemical Intermediates. 11:235-244
The absolute rate constanss for the gas-phase reactions of 1,1-dichlorosilylene with carbon monoxide and nitrous oxide have been determined using the flash photolysts-kinetic absorpiton spectroscopy technique. The bimolecular rate constant values at
Publikováno v:
Chemical Physics Letters. 45:449-453
Absolute rate constants were measured for the gas phase reactions of the CBr( ∼ X 2Π) radical produced in the flash photolysis of CHBr3 with a series of alkynes. The rate of addition to the triple bond followed the trend established for addition t
Publikováno v:
Chemical Physics Letters. 32:561-565
Diffusion coefficients for the system helium-nitrogen have been measured as a function of pressure at 300 K from 1 to 12.5 atmospheres. These measurements include composition dependences at 1, 3, 5 and 7 atmospheres. The results show reasonable agree
Publikováno v:
Chemical Physics Letters. 53:206-210
Absolute rate constants were measured for the gas phase reactions of the CCl(X 2 Π) radical produced in the flash photolysis of CHBr 2 Cl with a representative series of alkynes. The rate of addition to the triple bond follows the trend established