Zobrazeno 1 - 10
of 55
pro vyhledávání: '"T.E. Edmonds"'
Autor:
E.M. Palshis, T.E. Edmonds
Publikováno v:
Analytica Chimica Acta. 212:331-334
Cyclic voltammetry of reversible redox couples. e.g., hexacyanoferrate (III)/(II), at carbon fibre electrodes yields sigmoidal anodic and cathodic scans that are almost superimposed. However, the cyclic voltammogram of lead (II) ions was markedly dif
Publikováno v:
Analytica Chimica Acta. 187:293-299
The effect of temperature (0–60°C) on the operation of a piezoelectric gas monitor is discussed. The development and application of small solid-state systems incorporating Peltier devices to allow rapid thermal cycling or isothermal operation of t
Publikováno v:
Analytica Chimica Acta. 120:41-53
The differential pulse anodic stripping voltammetry of copper and lead at the mercury film glassy carbon electrode is discussed. The mercury film prevents the occurrence of a monolayer stripping peak for copper. The influence of antimony and bismuth
Publikováno v:
Analytica Chimica Acta. 129:69-77
The ionisation constants of unfractionated polymaleic acid, H 3 A, a synthetic analogue of fulvic acid, and the stability constants of its copper complexes were determined by differential pulse polarography. The ionisation constants are: p K 1 5.16,
Autor:
T.E. Edmonds
Publikováno v:
TrAC Trends in Analytical Chemistry. 4:220-224
A contemporary appraisal of chemical sensing in the environment reveals that there are few sound applications. This situation arises from the current state of sensor technology, rather than a lack of demand. A more strategic approach to the developme
Publikováno v:
Analytica Chimica Acta. 207:67-75
A technique for obtaining thin; evenly distributed manganese dioxide coatings by melting manganese nitrate is outlined. Responses of an AT-cut quartz piezoelectric crystal coated with manganese dioxide to nitrogen dioxide (12.5-10 000 μl 1−1) over
Autor:
T.E. Edmonds
Publikováno v:
Analytica Chimica Acta. 116:323-333
The differential pulse polarographic determination of molybdenum in nitrate media is described. The effects of pH, nitrate concentration, temperature, and cationic and anionic interferents on the peak current are reported. The detection limit is 0.45
Autor:
T.E. Edmonds, T.S. West
Publikováno v:
Analytica Chimica Acta. 117:147-157
The behavioural pattern of a coated piezoelectric crystal detector for the monitoring or traces of atmospheric gases partitioning into the coating on the crystal is predicted. The effects of variable experimental parameters such as detector cell volu
Publikováno v:
Analytica Chimica Acta. 212:23-30
The potentiometric response of several carbon fibres to hydrogen ion concentration (ph) was investigated. The effects of electrochemical pretreatment and the presence of complexes in the sample solution were studied. In solutions free of complexing a
Autor:
T.E. Edmonds, Ji Guoliang
Publikováno v:
Analytica Chimica Acta. 151:99-108
The analytical performance of micro-electrodes manufactured from several types of carbon fibre is investigated. The reduction of copper(II) in a chloride medium is used to assess this performance. Calibration curves in the 10–50 mg 1−1 range are