Výsledky vyhledávání - "T. W. Bentley"

water with acetone, ethanol, methanol, methanol-d, 50%methanol-d/50%D2O, and 2,2,2-trifluroethanol (TFE), and also in TFE-ethanol mixtures. The Grunwald-Winstein plot shows that the three aqueous mixtures exhibit dispersions into separate line. The c

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::05980b29014edc1be7cbb81df7841dcb
https://doi.org/10.5012/bkcs.2002.23.10.1445

Zobrazit plný text záznamu

Positioning solvolyses within the SN2-SN1 and SN3-SN2 spectrum of reaction mechanisms

Autor: Dennis N. Kevill, Hojune Choi, In Sun Koo, T. W. Bentley

Publikováno v: Journal of Physical Organic Chemistry. 30:e3585

A simple linear regression (Q equation) is devised to position solvolyses within the established SN2-SN1 spectrum of solvolysis mechanisms. Using 2-adamantyl tosylate as the SN1 model and methyl tosylate as the SN2 model, the equation is applied to s

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::fb56143408f2751f6fd65eb0b19fd58c
https://doi.org/10.1002/poc.3585

Zobrazit plný text záznamu

Substituent effects on the kinetic solvent isotope effect in solvolyses of arenesulphonyl chlorides

Autor: Jieun Oh, Kiyull Yang, T. W. Bentley, In Sun Koo, Ikchoon Lee

Publikováno v: Journal of Physical Organic Chemistry. 6:223-227

The Hammett type plot of kinetic solvent isotope effect (KSIE = k SOH /k SOD ), log(KSIE) vs σ, can be a useful mechanistic tool for solvolytic reactions. The slopes of such straight line plots for para-substituted benzenesulphonyl chlorides in meth

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::7130b0179aba92ddd8f452a044866d3a
https://doi.org/10.1002/poc.610060405

Zobrazit plný text záznamu

Vyhledávací nástroje:

Upřesnit hledání