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Publikováno v:
Journal of Alloys and Compounds. 278:165-168
The crystal chemistry of the non-stoichiometric compounds R(O,F)x with R=Tm, Yb, and Lu with x≈1.93±0.02, which are formed by peritectoid reaction of R2O3 with RF3 at ca. 900 K, ca. 950 K and 1076 K, respectively, has been studied by X-ray powder
Publikováno v:
Journal of Alloys and Compounds. 266:134-138
The rhombohedral(β)→cubic(α) phase transition of stoichiometric TmOF and the phase behaviour of samples of the analytical composition Tm(O,F)y with 1.85≤y≤2.10 were studied by quantitative differential thermal analysis (DTA) and by X-ray powd
Publikováno v:
Journal of Alloys and Compounds. 259:208-211
The rhombohedral-cubic phase transition typical of stoichiometric rare earth oxide fluorides of the formula type ROF was investigated for the ROF-based solid solution systems R 1− x Ca x O 1+ x F 1+ x , with RGd, Tb, Dy, by differential scanning
Publikováno v:
Thermochimica Acta. 276:1-6
The phase diagram of the binary system Sc 2 O 3 ScF 3 was investigated in the temperature range 1400–1840 K by quantitative differential thermal analysis (DTA). X-ray powder diffraction analysis revealed that at room temperature only the well-kn
Autor:
J.-H. Müller, T. Petzel
Publikováno v:
Journal of Alloys and Compounds. 224:18-21
The rhombohedral-cubic phase transition of ROF with R=Y, La, Nd, SmEr and the expansion coefficients of both modifications were studied by the high-temperature Guinier X-ray powder diffraction method. It was found that a constant formula volume in
Publikováno v:
Journal of Alloys and Compounds. 216:255-258
The crystal structure of A-Pr2O3 has been studied by X-ray powder diffraction and high-energy electron diffraction (HEED) from single crystals. The space group has been unambiguously established as P 3 m1 (No. 164) by HEED, though the intensities of
Publikováno v:
Materials Science Forum. :677-682
Publikováno v:
Journal of Alloys and Compounds. 200:27-31
The temperatures and enthalpies of the rhombohedral-cubic phase transition of stoichiometric ROF with R Y, La, Pr, Nd, SmEr, have been determined by differential scanning calorimetry. The temperatures of transition are found in the range 742
Publikováno v:
Journal of Alloys and Compounds. 196:121-125
Systematic phase studies on the system YbSe-Yb2Se3 revealed besides the two terminal compounds three intermediate phases Yb0.91Se, Yb0.83Se and Yb0.75Se, all of them without significant phase width, which is characteristic for the so-called room temp