Zobrazeno 1 - 10
of 23
pro vyhledávání: '"T. N. Khazanovich"'
Publikováno v:
Polymer Science Series A. 53:1086-1096
The viscoelasticity of a stretched polymer chain with its end particles exposed to oppositely acting forces is studied via collisional molecular dynamics and analytically. A simple model according to which a polymer molecule is a chain of particles l
Publikováno v:
Polymer Science Series A. 52:655-661
We study the extension of semiflexible (persistent) polymer chains composed of elastic bonds under the action of forces applied to their ends. For a given discrete model of a chain, the effective potential energy includes three components: the energy
Autor:
Nikolay K. Balabaev, T. N. Khazanovich
Publikováno v:
Russian Journal of Physical Chemistry B. 3:242-246
A relatively simple formula for the mean distance between the ends of a model chain composed of elastic freely joined segments as a function of an extending force applied to its ends was derived. It was assumed that the stiffness coefficient, which c
Publikováno v:
Polymer Science Series A. 50:1238-1247
The viscoelasticity of stretched polymer chains has been studied by the method of collisional dynamics. To this end, time correlation functions of the fluctuations of the microscopic stress tensor are modeled and relaxation moduli are expressed. Befo
Autor:
T. N. Khazanovich
Publikováno v:
Journal of Polymer Science Part C: Polymer Symposia. 16:2463-2468
The thermal diffusion coefficient in highly diluted polymer solutions is calculated. The pearl necklace model is used for description of flexible macromolecule dynamics. It is assumed that the usual diffusion equation holds under non-uniform temperat
Publikováno v:
Journal of Engineering Physics and Thermophysics. 76:604-609
Based on the previously developed molecular theory, we analyze experiments in which a small periodic deformation is applied to a statically extended elastomer and then the dynamic modulus is measured as a function of the static extension ratio λ. Th
Autor:
T. N. Khazanovich
Publikováno v:
Doklady Physical Chemistry. 425:66-68
Publikováno v:
Molecular Physics. 91:977-992
Intermolecular dipole± dipolar relaxation is considered in the framework of Red® eld equations describing the evolution of the spin density matrices for multicomponent solutions. Two types of contribution from intermolecular dipole± dipolar intera
Publikováno v:
Applied Magnetic Resonance. 10:413-429
The application of EPR spin probe and spin label technique for solving the two problems of polymer physical chemistry is considered. The first problem is the determination of conformational state and chain sizes in amorphous solid polymers. This dete
Autor:
K. T. Summanen, T. N. Khazanovich
Publikováno v:
International Journal of Polymeric Materials. 22:49-56
A theory of NMR of protons belonging to highly-stretched polymer chains with fixed ends, e.g. tie molecules of amorphous regions of oriented semicrystalline polymers, is presented. Analysis is carried out in terms of the model of freely-jointed chain