Zobrazeno 1 - 10
of 150
pro vyhledávání: '"T. L. Khotsyanova"'
Publikováno v:
Russian Chemical Bulletin. 48:906-913
Regularities of transmission of the effect of equatorial and axial substituents were established for a number of chlorine-containing organic compounds of pentatalent phosphorus using35Cl NQR spectra. The field constants of35Cl NQR frequencies of the
Publikováno v:
Scopus-Elsevier
The 55 Mn and 187 Re NQR spectral parameters for cyclopentadienyl tricarbonyl complexes of these metals at 77 K are presented. An analytical dependence between e 2 Qq zz and η has been shown to exist. Such dependence may be associated with slow mutu
Publikováno v:
Zeitschrift für Naturforschung A. 49:627-629
The 35Cl and 79,81Br NQR spectra of (C5H5)2M Hal2 (M = Ti, Mo, W, Zr, Hf; Hal = Cl, Br) are similar. They are quadruplets with splittings ranging from 2 to 7%. The averaged frequencies of chlorine and bromine are related by a linear dependence. The t
Autor:
L. D. Egorova, V. V. Saatsazov, I. N. Lisichkina, S. A. Petukhov, S. I. Gushchin, G. K. Semin, T. P. Tolstaya, T. L. Khotsyanova
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 34:913-917
1. For a series of iodonium compounds of the Ar2IX type, it has been found that the127I NQR parameters — the quadrupole coupling constant e2Qqzz, the asymmetry parameter η, and the frequency field constant ϖv/ϖEz -vary regularly with the nature
Autor:
T. A. Babushkina, N.N. Shmyreva, V.N. Pogorel'skaya, Yu.F. Shutilin, T. L. Khotsyanova, G. K. Semin, L.N. Gvozdeva, P.M. Gorbunov
Publikováno v:
Polymer Science U.S.S.R.. 23:1985-1991
A study has been made of molecular motion in oriented and nonoriented specimens of chloroprene rubber by methods of nuclear quadrupole resonance and radiothermoluminescence, as well as by a dynamic mechanical method using a torsion pendulum. The duct
Publikováno v:
Journal of Organometallic Chemistry. 88:351-356
The X-ray investigation of the title compounds has shown that in CH 3 COC 5 H 4 Mn(CO) 3 the orientation of CO groups with respect to the cyclopentadienyl ring is almost the same as in the unsubstituted manganese compound whereas in CH 3 COC 5 H 4 Re
Autor:
Yu. T. Struchkov, T. L. Khotsyanova
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 9:1275-1283
1. The crystal structure of 2,6-dichloro-4-nitrodimethylaniline was determined; the interatomic distances and valence angles were found with accuracies of ±0.01 A and ±2°, respectively. 2. Steric hindrance at CH3... Cl leads to rotation of the dim
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 9:292-299
1. Goniometric measurements were carried out on polyhalobenzenes and their derivatives (15 compounds in all) having substantial steric hindrance in their molecules. 2. The unit cell parameters, the space groups, and some other crystallochemical chara
Publikováno v:
Journal of Structural Chemistry. 10:435-438
Autor:
Yu. T. Struchkov, T. L. Khotsyanova
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 9:771-779
1. The coordinates of the atoms in the purely ionic structure of diphenyliodonium fluoborate were determined by a three-dimensional electron density series. 2. The bond lengths have the following values with an accuracy of ± 0.03 A: I-C=2.02, C-C=1.