Zobrazeno 1 - 10
of 36
pro vyhledávání: '"T. I. Yushmanova"'
Autor:
T. I. Yushmanova, V. Yu. Vitkovskii, E. N. Medvedeva, V. A. Lopyrev, Lyudmila V. Klyba, M. G. Voronkov
Publikováno v:
Journal of Fluorine Chemistry. 34:209-227
Main pathways in the electron-impact induced mass spectrometric fragmentation of hydrazides and alkylhydrazides of alkanecarboxylic acids have been studied. The effect of the structure of fluorinated acyl group and hydrocarbon radical on the dissocia
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 29:1911-1914
It has been demonstrated by means of19F NMR that l-acyl-2-alkyl (phenyl) hydrazines are the main products of the monoacylation of alkyl- and phenylhydrazine with derivatives of perfluorocarboxylic acids. The preferred conformations with respect to th
Autor:
T. I. Yushmanova, G. V. Rassolova, E. N. Medvedeva, V. A. Lopyrev, T. V. Kasfaik, S. M. Ponomareva
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 31:1965-1968
1. The NH acidity (pKa) of a series of carboxylic acid hydrazides and trifluoroacetamide in water was determined. 2. A linear dependence which correlated the pKa values of RCONHNH2 hydrazides with theσ* constants of the R substituents was found. The
Publikováno v:
Die Makromolekulare Chemie. 175:757-773
The cationic polymerization of vinylacetylenes can be implemented using an excess of catalysts, such as BF3O(C2H5)2, SnCl4, H2SO4, CCl3COOH, CF3COOH (20–50 mol per 100 mol monomer). This is due to the formation of a charge-transfer complex between
Autor:
T. I. Yushmanova, V. A. Lopyrev, M. G. Voronkov, E. N. Mevedeva, Nina N. Chipanina, G. I. Sarapulova, Yu. L. Frolov
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 29:1915-1919
1. The introduction of a phenyl or alkyl substituent at the β-nitrogen atom in the hydrazides of carboxylic acids and their fluorinated analogs leads to a trans orientation of the unshared pairs of electrons on the nitrogen atoms. 2. The influence o
Autor:
Nina N. Chipanina, G. V. Rassolova, L. I. Volkova, T. V. Kashik, Yu. L. Frolov, T. I. Yushmanova, V. A. Lopyrev, G. I. Sarapulova
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 35:942-945
1. The reaction of 1-fluoroacyl-1,2-dimethylhydrazides with phenol and trifluoroacetic acid in a medium of CCl4 and MeCN takes place with the formation of a molecular H complex, and the oxygen atom in the C=O group is the H bond acceptor in the hydra
Autor:
Yu. L. Frolov, L. I. Volkova, Nina N. Chipanina, T. I. Yushmanova, R. G. Sultangareev, N. A. Khlopenko, V. A. Lopyrev, G. I. Sarapulova
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 33:2056-2060
1. The absorption bands In the UV spectra of 1-methylhydrazides of aromatic acids have been assigned to specific types of electronic transitions. It has been shown that the amide fragment plays the decisive role in determining the nature of the elect
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 28:1760-1764
It was established by the1H and19F NMR method that the insertion of fluorine atoms in the acyl radical of mono- and diacylmethylhydrazines has a substantial effect on the population of the rotamers, without noticeably changing the activation energy o
Autor:
V. V. Keiko, V. A. Lopyrev, M. G. Voronkov, Nina N. Chipanina, Yu. L. Frolov, T. I. Yushmanova, E. N. Medvedeva, G. I. Sarapulova
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 30:557-560
1. The molecules of 1-acetyl-, 1-trifluoroacetyl-, and 1-difluoroacetyl-1,2-dimethylhydrazines form hydrogen bonds, which remain in dilute solutions and, partly, in the gaseous state. 2. Associations in 1-acetyl-1,2-dimethylhydrazine are evidently re
Publikováno v:
Polymer Science U.S.S.R.. 13:2319-2324