Zobrazeno 1 - 10
of 25
pro vyhledávání: '"T. David Westmoreland"'
Autor:
William S. Nelligan, Alison L. O'Neil, Andrea Roberts, T. David Westmoreland, Rachael Barlow, Camille Keeler
Publikováno v:
Journal of Chemical Education. 98:143-149
Developing a broadly based positive culture of safety in undergraduate instructional laboratory settings remains a significant challenge for chemical educators. An enhanced safety component has been developed for an upper-level laboratory course base
Autor:
Sen Wang, T. David Westmoreland
Publikováno v:
Inorganic Chemistry. 48:719-727
The syntheses and characterization of several complexes of Mn(II) with cyclen derivatives having variable numbers of pendant N-acetic acid or N-acetamide arms are reported. X-ray crystallographic results are presented for Mn(DOTAM)Cl(2) x 2 H(2)O (mo
Autor:
T. David Westmoreland
Publikováno v:
Inorganica Chimica Acta. 361:1187-1191
A symmetry analysis of the Berry pseudorotation of trigonal bipyramidal transition metal complexes is presented. Predictions are made regarding which electronic configurations are allowed to undergo pseudorotation and which configurations are symmetr
Autor:
T. David Westmoreland, Jacob Swann and
Publikováno v:
Inorganic Chemistry. 36:5348-5357
The electronic structures of the ions [MoOCl4]-, [MoOF5]2-, [MoOCl4(H2O)]-, and [MoOBr4(H2O)]- have been calculated by spin-polarized density functional calculations. The results confirm and extend previous calculations on these ions. In addition, th
Publikováno v:
Inorganic Chemistry. 35:7699-7703
Rate constants for the coupled two-electron/halide transfer self-exchange reactions of [Cp2MX]+ with Cp2M (M = Ru, Os; X = Cl, Br) have been measured in CD3CN at 298 K by 2D NMR spectroscopic techniques. Including data for the iodo complexes, the rat
Publikováno v:
Inorganic Chemistry. 35:7758-7768
The EPR spectroscopic parameters of a series of Mo(V) oxyhalide anions, [MoOX5-n(H2O)n](2-n)- (X = F, Br, n = 0; X = Cl, n = 1), were obtained in fluid solutions and frozen glasses or (X = Cl, Br) ...
Publikováno v:
Inorganic Chemistry. 34:3374-3377
Autor:
Sabrina G. Novick, Peter S. Dragovich, T. David Westmoreland, Timothy B. Karpishin, Edgar R. Civitello, John F. O'Connell, Geoffrey Bierach
Publikováno v:
Inorganic Chemistry. 32:237-241
Publikováno v:
Journal of Inorganic Biochemistry. 66:63-65
The treatment of xanthine oxidase with ethylisonitrile results in irreversible inhibition of the catalytic activity. Chemical and spectroscopic evidence suggests that the inhibited enzyme is a new distinct derivative in which the essential sulfido li
Publikováno v:
Organometallics. 15:4888-4890
[Cp2RuCl]PF6 reacts with benzylruthenocene in acetonitrile with a 1:1 stoichiometry to produce Cp2Ru and phenylruthenocenyl methylium cation. Similar hydride abstraction reactivity has also been ob...