Zobrazeno 1 - 10
of 90
pro vyhledávání: '"T. Adrian George"'
Publikováno v:
Polyhedron. 25:2721-2729
The title compound [Ni(4-NH2-C6H4CO2)2(CH3OH)2] · CH3OH (1) consists of Ni(II) atoms doubly bridged by p-aminobenzoate ligands (PAB) into 1D chains which are further connected into a 3D framework by methanol molecules through hydrogen bonding. Compo
Autor:
Kerry A Fusie Clark, T. Adrian George
Publikováno v:
Inorganic Chemistry. 44:416-422
The reactions of the lithium salts of the proligands P(C6H4-2-SH)3 (P(HSH)3), P(C6H3-3-SiMe3-2-SH)3 (P(TMSSH)3), and P(C6H3-5-Me-2-SH)3 (P(MeSH)3) with RSnCl3 (R = Ph, Me, n-Bu), in THF at 0 °C, pr...
Publikováno v:
Inorganica Chimica Acta. 281:153-159
The reduction of [MoCl3(TRI)], where TRI=PhP(CH2CH2PPh2)2, with sodium amalgam in benzene, toluene or anisole resulted in the formation of the corresponding [Mo(ν6-arene)(TRI)] complex. Each complex displayed a reversible one-electron oxidation in t
Autor:
Charles R. Ross, T. Adrian George, Jeffrey R.D. Debord, John J. Stezowski, Jodi D. Niemoth-Anderson
Publikováno v:
Polyhedron. 15:4031-4040
The phenyldiazenido complexes [MCl(NNPh)(PMe 2 Ph) 4 ] (M = Mo,W) and phenyl- and diorganohydrazido(2-) complexes [WCl 2 (NN(H)Ph)(PMe 2 Ph) 3 ], [MCl 2 (NNRR′)(PMe 2 Ph) 3 ]] (M = Mo, W ; R = R′ = Me, R = R′ = Ph ; M = W, R = Me, R′ = Ph), [
Publikováno v:
Journal of Coordination Chemistry. 35:349-357
Reactions of HBr with trans-[W(N2)2(dppe)PPh2Me)2] (1) (dppe = Ph2CH2CH2PPh2) result in protonation of coordinated N2 but no formation of ammonia or hydrazine. The tungsten-containing product depends upon the reaction conditions: (i) in MeOH, the pro
Publikováno v:
Inorganic Chemistry. 34:1295-1298
Publikováno v:
Polyhedron. 10:467-470
The reaction of HBr with trans-[Mo(N2)2(dppee)(PR3)] (1), where dppee = O(CH2CH2PPh2)2 and PR3 = PPh3, PPh2Me, in CH2Cl2 yields a hydrazido(2-) complex which reacts further to form ammonia and hydrazine. During this reaction an intermediate can be is
Autor:
T. Adrian George, Bharat B. Kaul
Publikováno v:
Inorganic Chemistry. 29:4969-4974
Studies of the reactions of acid with a bis(dinitrogen) complex of molybdenum anchored to a polymer support provide valuable information concerning the mechanism of nitrogen fixation. Two methods have been developed for attaching {Mo(N 2 ) 2 } to a m
Publikováno v:
Inorganic Chemistry. 29:4789-4796
The reactions of a series of mono(dinitrogen) complexes of molybdenum Mo(N 2 )(dpepp)(L 2 ) [where dpepp=PhP(CH 2 CH 2 PPh 2 ) 2 and L 2 =PMe 2 Ph, Me 2 PCH 2 PMe 2 (dmpm), 1,2-(Me 2 As) 2 C 6 H 4 (diars), Ph 2 PCH 2 PPh 2 (dppm), Ph 2 PCH 2 CH 2 PPh
Autor:
Lidun Ma, Shadid N. Shaikh, Robert C. Tisdale, Kassu Gebreyes, Lenore M. Koczon, Jon Zubieta, T. Adrian George
Publikováno v:
Polyhedron. 9:545-551
The reactions of anhydrous HX (X = Br, Cl) with trans-Mo(N2)2(triphos) (PPh3) (1) where triphos = PhP(CH2CH2PPh2)2, yield [MoX(NNH2)(triphos)(PPh3)]X as a mixture of isomers: 1A(X) and 1B(X). In solution, PPh3 dissociates rapidly from the B isomer. A