Zobrazeno 1 - 10
of 227
pro vyhledávání: '"T V, RajanBabu"'
Publikováno v:
Dalton Transactions. 51:10148-10159
New synthesis of (L)[CoIX]-complexes from (L)CoX2 and Mashima's reagent.
Autor:
Stanley M. Jing, Vinayak Vishnu Pagar, Mahesh M. Parsutkar, Souvagya Biswas, T. V. RajanBabu, James H. Herbort
Publikováno v:
Acc Chem Res
ConspectusOne of the major challenges facing organic synthesis in the 21st century is the utilization of abundantly available feedstock chemicals for fine chemical synthesis. Regio- and enantioselective union of easily accessible 1,3-dienes and other
Autor:
Dipshi Singh, T. V. RajanBabu
Publikováno v:
Angewandte Chemie International Edition. 62
Alkynes and 1,3-dienes are among the most readily available precursors for organic synthesis. We report two distinctly different, catalyst-dependent, modes of regio- and enantioselective cycloaddition reactions between these classes of compounds prov
Publikováno v:
ACS Catal
(E)-2-Trialkylsilyloxy-1,3-dienes and the corresponding 2-acetoxy derivatives participate in cobalt-catalyzed heterodimerization reactions with ethylene, giving mostly 4,1-hydrovinylation products with addition of the vinyl group to C(4) and H at C(1
Publikováno v:
ACS Catalysis. 11:9605-9617
Two intermolecular hydroalkenylation reactions of 1,6-enynes are presented which yield substituted 5-membered carbo- and -heterocycles. This reactivity is enabled by a cationic bis-diphenylphosphinopropane (DPPP)CoI species which forms a cobaltacyclo
Autor:
Bill Nugent, T. V. RajanBabu
Publikováno v:
Angewandte Chemie. 133:2222-2229
Autor:
William A. Nugent, T. V. RajanBabu
Publikováno v:
Angew Chem Int Ed Engl
While writing a comprehensive review on the reactions of epoxides with titanium(III) reagents, we encountered a series of mechanistic puzzles. Using clues from the literature, many of which were not available at the time that the mysteries emerged, i
Publikováno v:
ACS catalysis. 11(15)
Two intermolecular hydroalkenylation reactions of 1,6-enynes are presented which yield substituted 5-membered carbo- and -heterocycles. This reactivity is enabled by a cationic
Autor:
Mahesh M. Parsutkar, T. V. RajanBabu
Publikováno v:
J Am Chem Soc
Ketones are among the most widely used intermediates in organic synthesis, and their synthesis from inexpensive feedstocks could be quite impactful. Regio- and enantioselective hydroacylation reactions of dienes provide facile entry into useful keton