Zobrazeno 1 - 10
of 23
pro vyhledávání: '"Susan M. Tarr"'
Publikováno v:
The Journal of Chemical Physics. 75:2786-2794
The nondissociative electron impact ionization cross section of the metastable N2(A 3Σ+u) state is measured from threshold to 240 eV. Rising from an appearance potential of 10.1±0.6 eV, the cross section peaks at about 40 eV with a value of (1.14±
Autor:
Susan M. Tarr, Herschel Rabitz
Publikováno v:
The Journal of Chemical Physics. 70:2569-2573
The relaxation behavior of the He–HD system is studied by applying an exponential distorted wave procedure to calculate the cross sections and the rate constants for vibrational–rotational energy transfer in the vibrational manifolds n, 0⩽n⩽5
Publikováno v:
The Journal of Chemical Physics. 74:2869-2878
High‐Rydberg (HR) molecules of H2, D2, N2, and CO have been observed with lifetimes of the order of 100 μsec. They are stable with respect to predissociation and autoionization and have sufficiently long radiative lifetimes to be detected because
Publikováno v:
The Journal of Chemical Physics. 79:213-219
In this work we report the observation of polyatomic high‐Rydberg molecules which survive for several hundred microseconds. Methane and ethane were excited by electron impact to produce high‐Rydberg states of their fragments: CH3 from methane and
Autor:
Susan M. Tarr, Herschel Rabitz
Publikováno v:
The Journal of Chemical Physics. 68:642-646
An inexpensive and accurate technique for computing inelastic cross sections has been developed by combining an exponential distorted wave (EDW) approximation and an effective Hamiltonian. This procedure is implemented through the use of uniformized
Publikováno v:
Physical Review A. 20:71-81
High-Rydberg atoms are produced by an electron beam passing through each of the rare gases at \ensuremath{\sim}${10}^{\ensuremath{-}6}$ Torr and are detected by electric field ionization after traveling 20.1 cm at thermal velocity. Their principal qu
Publikováno v:
The Journal of Chemical Physics. 70:4468-4473
The production of high‐Rydberg (HR) atomic fragments by electron‐impact dissociation of 13 molecules has been compared to the results of previous work on the production of HR rare gas atoms. Measurements have been made of principal quantum number
Autor:
Susan M. Tarr, Herschel Rabitz
Publikováno v:
The Journal of Chemical Physics. 68:647-651
The vibrational–rotational relaxation of He–H2 at high temperatures is studied by applying a recently developed exponential distorted wave (EDW) technique to calculate inelastic cross sections. Particular attention is given to the role of the hig
Publikováno v:
Physical Review Letters. 44:1660-1663
Threshold-energy peaks are observed for electron impact excitation of N/sub 2/ and H/sub 2/ to high-Rydberg states. These peaks are attributed to the direct excitation of high-lambda states near threshold consistent with the prediction of Fano.
The centrifugal decoupling approximation previously employed in quantum mechanics is extended to classical mechanics. Both classical and quantum centrifugal decoupling (CCD and CD, respectively) calculations are performed for HCl–Ar. Total cross se
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https://resolver.caltech.edu/CaltechAUTHORS:TARjcp77
https://resolver.caltech.edu/CaltechAUTHORS:TARjcp77