Zobrazeno 1 - 10
of 12
pro vyhledávání: '"Susan M. Stevenson"'
Autor:
Alice R. Wong, Nicholas J. Fastuca, Victor W. Mak, Jeffrey K. Kerkovius, Susan M. Stevenson, Sarah E. Reisman
Publikováno v:
ACS Central Science, Vol 7, Iss 8, Pp 1311-1316 (2021)
Externí odkaz:
https://doaj.org/article/99198d4f496b442984be9c32419bc220
Autor:
Jeffrey K. Kerkovius, Nicholas J. Fastuca, Alice R. Wong, Sarah E. Reisman, Susan M. Stevenson, Victor W. Mak
Publikováno v:
ACS Central Science, Vol 7, Iss 8, Pp 1311-1316 (2021)
The C19 diterpenoid alkaloids (C19 DTAs) are a large family of natural products, many of which modulate the activity of ion channels in vivo and are therefore of interest for the study of neurological and cardiovascular diseases. The complex architec
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::85bc2f01558fd1ff3657a268052cacad
https://doi.org/10.1021/acscentsci.1c00540
https://doi.org/10.1021/acscentsci.1c00540
Publikováno v:
Chemical Science
A Cr-photocatalyzed [4 + 2] cycloaddition between dienes and electron-deficient alkenes is reported, accessed by up to three converging pathways to yield the “meta” adducts.
A chromium-catalyzed, visible light-activated net [4 + 2] cycloaddi
A chromium-catalyzed, visible light-activated net [4 + 2] cycloaddi
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::eb8f02f1dbfd5e09e1128d27eafa2688
https://doi.org/10.1039/c6sc03303b
https://doi.org/10.1039/c6sc03303b
Autor:
Robert F. Higgins, Niels H. Damrauer, Eric M. Ferreira, Steven M. Fatur, Samuel G. Shepard, Matthew P. Shores, David J. Boston, Susan M. Stevenson, Anthony K. Rappé
Publikováno v:
Journal of the American Chemical Society. 138:5451-5464
A combined experimental and theoretical investigation aims to elucidate the necessary roles of oxygen in photoredox catalysis of radical cation based Diels-Alder cycloadditions mediated by the first-row transition metal complex [Cr(Ph2phen)3](3+), wh
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::7000f23c2733d12c32b0ae6a747c9365
https://doi.org/10.1021/jacs.6b02723
https://doi.org/10.1021/jacs.6b02723
Publikováno v:
Organic Chemistry Frontiers. 3:1228-1235
A full account of our investigation of C–C bond migration in the cycloisomerization of oxygen-tethered 1,6-enynes is described. Under Pt(II) and/or Ir(I) catalysis, cyclic and acylic alkyl groups were found to undergo 1,2-shifts into metal carbenoi
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::32acfc200af04f99aeedc05e49f513d9
https://doi.org/10.1039/c6qo00224b
https://doi.org/10.1039/c6qo00224b
Autor:
J. Patrick Lutz, Casey E. Baxter, Breanna M. Powell, John M. Zona, Colin M. Rathbun, Timothy S. Boman, Jeffrey B. Johnson, Susan M. Stevenson
Publikováno v:
Journal of the American Chemical Society. 134:715-722
Rhodium-catalyzed intramolecular carboacylation of alkenes, achieved using quinolinyl ketones containing tethered alkenes, proceeds via the activation and functionalization of a carbon-carbon single bond. This transformation has been demonstrated usi
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::5f9b0d4d0b25388e8961c45c5da511b6
https://doi.org/10.1021/ja210307s
https://doi.org/10.1021/ja210307s
Publikováno v:
Chem. Commun.. 50:5239-5241
A C-C bond migration event during the cycloisomerization of 1,6-enynes is described. Two different catalytic systems, iridium- or platinum-based, are able to induce this process. Alkyl migrations of larger rings and acyclic groups indicate that the r
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::9523e5ca8d309118245a906a222fea13
https://doi.org/10.1039/c3cc47499b
https://doi.org/10.1039/c3cc47499b
Publikováno v:
ChemInform. 46
Optimal reactivity for these cycloadditions is observed using near UV irradiation; visible-light promotion is effective too, albeit with lower yields.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::d1841d836a7cf0ef5f67c4db9669398d
https://doi.org/10.1002/chin.201538070
https://doi.org/10.1002/chin.201538070
Publikováno v:
ChemInform. 45
C—C bond migration into metal carbenoid intermediates generated through the cycloisomerization of oxygen-tethered 1,6-enynes (I) and (III) is reported.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::50e3489326a27f653d828d0b14a34af0
https://doi.org/10.1002/chin.201445152
https://doi.org/10.1002/chin.201445152