Zobrazeno 1 - 10
of 19
pro vyhledávání: '"Suprava Nayak"'
Publikováno v:
Asian Journal of Chemistry. 31:2022-2028
A new octahedral cobalt(III) complex of 1,5-bis(2-hydroxybenzamido)-3-aza pentane was synthesized and characterized by elemental analysis, UV-visible, IR, mass spectrometry and thermal analysis methods. Oxidative behaviour of the complex towards the
Publikováno v:
Transition Metal Chemistry. 39:177-187
The reduction of the octahedral cobalt(III) complex CoIII(HL)·9H2O, H4L = 1,8-bis(2-hydroxybenzamido)-3,6-diazaoctane by glutathione (GSH) has been studied by conventional spectrophotometry at 25.0 ≤ t/°C ≤ 45.0, 0.02 ≤ [H+]/mol dm−3 ≤ 0.
Publikováno v:
Polyhedron. 30:1637-1645
The oxidation of glyoxylic acid (HGl) by MnIVL {L4− = tetra deprotonated 1,8-bis(2-hydroxybenzamido)-3,6-diazaoctane} was investigated in the pH range 1.67–10.18, at 25–45 °C and 0.5 M ionic strength. The reaction exhibited biphasic kinetics w
Publikováno v:
Transition Metal Chemistry. 33:39-53
The octahedral complex, [CoIII(HL)]·9H2O (H4L = (1,8)-bis(2-hydroxybenzamido)-3,6-diazaoctane) incorporating bis carboxamido-N-, bis sec-NH, phenolate, and phenol coordination has been synthesized and characterized by analytical, NMR (1H, 13C), e.s.
Autor:
Anadi C. Dash, Suprava Nayak
Publikováno v:
Transition Metal Chemistry. 31:930-937
The redox reactions of thiosulfate with four iron(III) complexes having phenolate-amide-amine coordination, FeIII(L){L = 1,2-bis(2-hydroxybenzamido)ethane, L1; 1,3-bis(2-hydroxybenzamido)propane, L2; 1,5-bis(2-hydroxybenzamido)3-azapentane, L3; and 1
Autor:
Suprava Nayak, Anadi C. Dash
Publikováno v:
Transition Metal Chemistry. 31:316-324
The MnIV complex of 1,8-bis(2-hydroxybenzamido)-3,6-diazaoctane (MnIVL) with phenolate-amido-amine coordination is reduced by l-ascorbic acid and oxalic acid obeying overall 1:1 stoichiometry. The reactions are biphasic and MnIIIL− is the reactive
Publikováno v:
Transition Metal Chemistry. 30:917-932
Autor:
Anadi C. Dash, Suprava Nayak
Publikováno v:
Transition Metal Chemistry. 30:560-568
The MnIV complex of tetra-deprotonated 1,8-bis(2-hydroxybenzamide)-3,6-diazaoctane (MnIVL) engrossed in phenolate-amido-amine coordination is reduced by HSO 3 − and SO 3 2− in the pH range 3.15–7.3 displaying biphasic kinetics, the MnIIIL− be
Autor:
Anadi C. Dash, Suprava Nayak
Publikováno v:
Journal of Chemical Sciences. 116:133-142
An O-bonded sulphito complex, Rh(OH2)5(OSO2H)2+, is reversibly formed in the stoppedflow time scale when Rh(OH2) 6 3+ and SO2/HSO 3 − buffer (1
Publikováno v:
Australian Journal of Chemistry. 65:113
The formation of an intermediate ruthenium(iii) thiolate complex by the interaction of thiols, RSH (R = glutathione and l-cysteine) and dichlorotetraaquaruthenium(iii), [RuIIICl2(H2O)4]+, is reported in the temperature range 25–40°C. The kinetics