Sensing alterations of the local environment of 3d, 4d, and 4f central ions in polyoxopalladates with soft X-ray magnetic dichroisms

Autor: Schmitz-Antoniak, Carolin, Izarova, Natalya V., Stuckart, Maria, Smekhova, Alevtina, Schmitz, Detlef, Shams, S. Fatemeh, Siemensmeyer, Konrad, Giesen, Margret, Kögerler, Paul

Publikováno v: In Journal of Magnetism and Magnetic Materials 15 November 2020 514

Intramolecular crossover from unconventional diamagnetism to paramagnetism of palladium ions probed by soft X-ray magnetic circular dichroism

Autor: Smekhova, Alevtina, Schmitz, Detlef, Izarova, Natalya V., Stuckart, Maria, Shams, S. Fatemeh, Siemensmeyer, Konrad, de Groot, Frank M.F., Kögerler, Paul, Schmitz-Antoniak, Carolin, Sub Inorganic Chemistry and Catalysis, Inorganic Chemistry and Catalysis

Publikováno v: Communications Chemistry, 3(1), 1. Springer Nature

The case of palladium(II) ions in molecular polyoxopalladates highlights the importance of accounting not only for nearest neighbour atoms or ions in order to understand, model or predict magnetic characteristics. Here, using site-specific soft X-ray

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=narcis______::3e9cd305b12944e66f38e3a66bd70d6a
https://dspace.library.uu.nl/handle/1874/424909

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Polyoxopalladates as Prototype Molecular Hydrogen Uptake Systems and Novel In situ Hydrogen Detectors on the Nanoscale

Autor: Schmitz-Antoniak, Carolin, Izarova, Natalya V., Svechkina, Nataliya, Smekhova, Alevtina, Stuckart, Maria, Schmitz, Detlef, Kögerler, Paul

Publikováno v: European journal of inorganic chemistry 2019(3-4), 448-455 (2019). doi:10.1002/ejic.201800972
European journal of inorganic chemistry 2019(3/4), 448-455 (2019). doi:10.1002/ejic.201800972 special issue: "Special Issue: Celebrating Polyoxometalates (Cluster Issue)"

European journal of inorganic chemistry 2019(3/4), 448-455 (2019). doi:10.1002/ejic.201800972 special issue: "Special Issue: Celebrating Polyoxometalates (Cluster Issue)"
Published by Wiley-VCH, Weinheim

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::6ed8a4d7d0a7deea3719ecabd4693efd

Probing Frontier Orbital Energies of {Co 9 (P 2 W 15 ) 3 } Polyoxometalate Clusters at Molecule–Metal and Molecule–Water Interfaces

Autor: Yi, Xiaofeng, Izarova, Natalya V., Stuckart, Maria, Thomas, Louis, Vuillaume, Dominique, Van Leusen, Jan, Duchon, Tomas, Nemsak, Slavomir, Bourone, Svenja D. M., Schmitz, Sebastian, Izarova, Natalya, Guerin, David, Lenfant, Stéphane, Duchoň, Tomáš, Nemšák, Slavomír, Bourone, Svenja, Kögerler, Paul

Publikováno v: Journal of the American Chemical Society
Journal of the American Chemical Society, 2017, 139 (41), pp.14501-14510. ⟨10.1021/jacs.7b07034⟩
Journal of the American Chemical Society, American Chemical Society, 2017, 139 (41), pp.14501-14510. ⟨10.1021/jacs.7b07034⟩
Journal of the American Chemical Society, vol 139, iss 41
Journal of the American Chemical Society 139(41), 14501-14510 (2017). doi:10.1021/jacs.7b07034

Functionalization of polyoxotungstates with organoarsonate co-ligands enabling surface decoration was explored for the triangular cluster architectures of the composition [CoII9(H2O)6(OH)3(p-RC6H4AsVO3)2({\alpha}-PV2WVI15O56)3]25-({Co9(P2W15)3}, R =

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::2ac239fa796f503a99e7d315010fb6cb
https://hal.science/hal-02133798