Zobrazeno 1 - 10
of 33
pro vyhledávání: '"Steven R, Goates"'
Publikováno v:
Applied Spectroscopy. 75:1461-1464
Often only small amounts of sample are available for spectroscopic analytical determinations. This work investigates the enhancement of signal in columns packed with silica particles. We propose that silica particles cause the light to scatter throug
Publikováno v:
Journal of Chromatography A. 1417:73-78
Portable and compact instruments for separating and detecting organic compounds are needed in the field for environmental studies. This is especially the case for pollution studies as in-field detection of organic compounds helps identify sources of
Publikováno v:
Analytical Chemistry. 84:1862-1870
In vibrationally resonant sum-frequency generation (VR-SFG) spectra, the resonant signal contains information about the molecular structure of the interface, whereas the nonresonant signal is commonly treated as a background and has been assumed to b
Publikováno v:
Journal of Chromatography A. 1216:5588-5593
Density gradients in packed capillary columns operating under the extreme pressure drops typical for solvating gas chromatography were investigated by on-column spectroscopic measurements and compared to a theoretical model. Laser-induced fluorescenc
Publikováno v:
Journal of Chromatography A. 1216:5594-5599
To investigate how fluid compressibility affects efficiency in supercritical fluid separations, band dispersion along a packed capillary column was measured from on-column elution rate profiles obtained under solvating gas chromatography (SGC) condit
Publikováno v:
Applied Spectroscopy. 63:108-111
Efforts to understand and optimize separations employing compressible mobile phases have been limited by a lack of understanding of the mobile phase density gradient. Mobile phase compressibility leads to gradients in linear velocity and solute reten
Publikováno v:
Langmuir. 15:1400-1409
Sum-frequency spectroscopy and ellipsometry have been used to study monolayers of the nonionic surfactants poly(ethylene glycol) monododecyl ethers (C12Em; m = 2−8) at the air−water interface. SF spectra were acquired for areas of 30−70 A2 per
Publikováno v:
The Journal of Physical Chemistry. 99:13461-13466
The ring-closure reaction of M(CO){sub 5}L-L (M = W, Mo) where L-L denotes a bidentate ligand was chosen for its comparative independence of solvent properties to demonstrate the repulsive (or intrinsic) part of the activation volume. The ring-closur
Publikováno v:
Review of Scientific Instruments. 66:222-226
A high‐pressure optical cell has been designed that achieves an effective separation between the chemical sample and the pressurizing medium and system. This design limits possible sample contamination and catalytic effects under supercritical flui
Autor:
David J. Dixon, Steven R. Goates, Keith P. Johnston, Milton L. Lee, Sheldon R. Sumpter, Steven H. Page
Publikováno v:
The Journal of Supercritical Fluids. 6:95-101
Because the phase behavior of the mobile phase must be known before conclusions from supercritical-fluid chromatography (SFC) can be considered reliable, the phase behaviors of tri- n -butylphos-phate/C0 2 and acetone/CO 2 were thoroughly determined