Zobrazeno 1 - 10
of 354
pro vyhledávání: '"Stephen F. Nelsen"'
Autor:
Yen-Ting Chen, Stephen F. Nelsen, Jeffrey I. Zink, Matthew D. Kiesz, Ryan M. Hoekstra, João P. Telo
Publikováno v:
The Journal of Physical Chemistry A. 118:11490-11498
The electronic absorption spectrum of 9,9-dimethyl-2,7-dinitrofluorene radical anion in HMPA displays both a NIR intervalence charge transfer and a visible excited state mixed valence transition. These transitions contain a similar vibronic progressi
Autor:
Frank Weinhold, Clauss Allen David, Mohamed Ayoub, John W. Moore, Stephen F. Nelsen, Clark R. Landis
Publikováno v:
Chem. Educ. Res. Pract.. 15:417-434
We describe the logical flaws, experimental contradictions, and unfortunate educational repercussions of common student misconceptions regarding the shapes and properties of lone pairs, inspired by overemphasis on “valence shell electron pair repul
Publikováno v:
The Journal of Organic Chemistry. 78:11373-11381
We report synthesis and investigation of doubly trimethylene-bridged tetrabenzyl-p-phenylenediamine 1(Bz) in its singly and doubly charged redox states. The singly oxidized monoradical cation, which is a mixed-valence (MV) system with directly intera
Autor:
Jeffrey I. Zink, Keiji Okada, Stephen F. Nelsen, Ryan M. Hoekstra, Michael N. Weaver, Marcelle Dibrelle
Publikováno v:
Journal of Physical Organic Chemistry. 25:578-585
The optical and resonance Raman spectra of the 2,2′: 6′,2″:6″,6-trioxytriphenyl-amine cation are measured and interpreted. This molecule contains two simultaneous types of coupling between three chromophores and two types of bridging atoms. T
Publikováno v:
The Journal of Physical Chemistry A. 115:3016-3021
Optical and electron paramagnetic resonance spectroscopies were used to study the radical anions of several m-dinitrobenzenes and p-dinitrobenzenes with substituents on ortho positions relative to the nitro groups. 1,4-Dinitrobenzene, 1,4-dimethyl-2,
Publikováno v:
Journal of the American Chemical Society. 132:6176-6182
X-ray crystallographic structures are reported for 1(Me)(2+)(SbCl(6)(-))(2) x 2 CH(3)CN, 2(Et)(2+)(SbF(6)(-))(2) x 2 CH(3)CN x 2 CH(2)Cl(2), and 1(iPr)(2+)(SbF(6)(-))(2), which also contained unresolved solvent and is in a completely different confor
Publikováno v:
Journal of Physical Organic Chemistry. 22:522-526
The optical absorption spectrum and resonance Raman enhancement of the lowest energy absorption band of K+7,7,8,8-tetracyanoquinodimethane− (TCNQ) are reported and examined in the mixed valence (MV) framework. The absorption spectrum is assigned, i
Autor:
Jenny V. Lockard, Michael N. Weaver, Stephen F. Nelsen, Xianghuai Wang, Yun Luo, Edward A. Plummer, Jeffrey I. Zink, Guadalupe Valverde-Aguilar
Publikováno v:
The Journal of Physical Chemistry A. 112:7332-7341
Absorption spectra for 2,3-diaryl-2,3-diazabicyclo[2.2.2]octane radical cations (2(X)(*+)) and for their monoaryl analogues 2-tert-butyl-3-aryl-2,3-diazabicyclo[2.2.2]octane radical cations (1(X)(*+)) having para chloro, bromo, iodo, cyano, phenyl, a
Publikováno v:
The Journal of Physical Chemistry A. 111:10993-10997
Optical spectra in dimethylformamide are reported for the radical anions of benzoquinone, its tetramethyl and tetrachloro analogues, and tetra-ortho-alkyl derivatives of biphenyl, stilbene, terphenyl, quadriphenyl, and 1,4-bis(2-phenylethenyl)benzene
Autor:
Xianghuai Wang, Stephen F. Nelsen, Guadalupe Valverde-Aguilar, Jeffrey I. Zink, Michael N. Weaver
Publikováno v:
The Journal of Physical Chemistry A. 111:5441-5447
Resonance Raman and absorption spectra of 9,10-bis(2-tert-butyl-2,3-diazabicyclo[2.2.2]oct-3-yl)-anthracene (2) are measured and analyzed. The contribution of the individual vibrational normal modes to the reorganization energy is investigated. Excit