Zobrazeno 1 - 7
of 7
pro vyhledávání: '"Stephen D. J. McKinnon"'
Publikováno v:
Inorganic Chemistry. 52:8053-8066
The electronic structures of (LX)2Ru(Vd)Ru(LX)2 complexes (Vd = 1,5-diisopropyl-3-(4,6-dimethyl-2-pyrimidinyl)-6-oxoverdazyl radical; LX = acac (acetylacetonate) or hfac (hexafluoroacetylacetonate)) in multiple charge states have been investigated ex
Publikováno v:
J. Mater. Chem.. 21:1523-1530
The synthesis, structures, and magnetic properties of several Pd(II) and Pt(II) complexes of verdazyl radicals are presented. Reactions of bidentate verdazyl radicals with (RCN)2MCl2 (R = Me or Ph; M = Pd or Pt) produced square planar (verdazyl)MCl2
Publikováno v:
Organic Letters. 9:4837-4840
The redox properties of verdazyl radicals are presented using cyclic voltammetry techniques. These radicals can be reversibly reduced as well as oxidized. Electron-donating and -withdrawing substituents have significant effects on the oxidation and r
Publikováno v:
Chem. Commun.. 46:773-775
Spectroscopic, structural, and computational studies of verdazyl radical-ruthenium complexes reveal the verdazyl to be a redox-active and non-innocent ligand. The ensuing delocalization of charge is highly sensitive to the nature of the beta-diketona
Publikováno v:
Journal of the American Chemical Society. 133(34)
The electronic structures of (Vd)Ru(LX)(2) complexes (Vd = 1,5-diisopropyl-3-(2-pyridyl)-6-oxoverdazyl radical; LX = acac or hfac) as neutral, cationic, and anionic species have been investigated experimentally and computationally to probe the interp
Publikováno v:
Dalton Transactions. 42:16829
The synthesis and characterization of two new N,N'-diarylverdazyl radical ligands and their corresponding PdCl2 complexes are described. One of the two radicals is of the "Kuhn verdazyl" structure type and was made by adaptation of standard synthetic
Publikováno v:
Organic Letters; Nov2007, Vol. 9 Issue 23, p4837-4840, 4p