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Autor:
Stephanie F. Maggio, Aspen L. Settle, Andrew T. Milcarek, Emmanuel A. Theodorakis, Maria A. Theodoraki, Oraphin Chantarasriwong, Mary L. Alpaugh, Tanis J. Dorwart, Theodore Habarth Morales
Publikováno v:
Bioorganic chemistry. 93
Racemic resolution of (+/-)-MAD28, a representative caged xanthone, was accomplished using (1S, 4R)-(-)-camphanic chloride as the chiral agent. Selective crystallization of the resulting diastereomers in acetonitrile produced, after hydrolysis, the p