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Autor:
Ethan M. Healy, Jane M. Owens, Stephanie E. Koon-Church, Kathleen P. Cuddihy, Walter J. Bowyer, Bridget J. Beals, Zainab I. Bello, Cynthia E. Teerlinck
Publikováno v:
The Journal of Physical Chemistry A. 106:498-503
This paper reports the first absolute rate constants for the formation of Grignard reagents from magnesium metal and organohalides. The theory that allows calculation of heterogeneous rate constants from the rate of growth of individual pits is descr