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pro vyhledávání: '"Stephanie E. Koon"'
Autor:
Ethan M. Healy, Jane M. Owens, Stephanie E. Koon-Church, Kathleen P. Cuddihy, Walter J. Bowyer, Bridget J. Beals, Zainab I. Bello, Cynthia E. Teerlinck
Publikováno v:
The Journal of Physical Chemistry A. 106:498-503
This paper reports the first absolute rate constants for the formation of Grignard reagents from magnesium metal and organohalides. The theory that allows calculation of heterogeneous rate constants from the rate of growth of individual pits is descr
Publikováno v:
The Journal of Organic Chemistry. 58:3225-3226
Magnesium surfaces are photographed is situ during the formation of Grignard reagent (in the presence of an indicator) in order to study the mechanism and to undertand the reactivity of magnesium surfaces