Zobrazeno 1 - 3
of 3
pro vyhledávání: '"Stephanie A. Antolak"'
Publikováno v:
Biochemical and Biophysical Research Communications. 358:363-367
As part of the pksX gene cluster of Bacillus subtilis strain 168, pksS has been preliminarily annotated as a cytochrome P450 homolog that hydroxylates the polyketide product of this cluster, which was recently shown to be involved in the biosynthesis
Publikováno v:
ChemInform. 46
Upon deprotonation, title compounds (I) undergo ring contraction to the corresponding quinolone-2,4-diones (II) with high enantioselectivity.
Publikováno v:
Organic letters. 16(19)
N1-Methyl-N4-Boc-benzo[e][1,4]diazepine-2,5-diones were prepared in good yield and high stereochemical purity from five amino acids. Upon deprotonation, these compounds undergo ring contraction to the corresponding quinolone-2,4-diones with high enan