Výsledky vyhledávání - "Stefano Piscitelli"

One-Pot Gold-Catalyzed Synthesis of Azepino[1,2-a]indoles

Autor: Marco Bandini, Michel Chiarucci, Rubén S. Ramón, Giancarlo Fabrizi, Antonella Goggiamani, Gianpiero Cera, Steven P. Nolan, Stefano Piscitelli

Publikováno v: Angewandte Chemie. 124:10029-10033

Indoles from scratch: A gold(I)/N-heterocyclic carbene complex (IPr=1,3-di(isopropylphenyl)imidazol-2-ylidene) was found to be particularly effective as a catalyst, enabling the one-pot synthesis of tricyclic azepinoindoles by an unprecedented cascad

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::d74d0923f55c37fb01a7738c0dab7909
https://doi.org/10.1002/ange.201205463

Zobrazit plný text záznamu

The authors developed a gold-cat- alyzed hydroamination followed by an asymmetric nucleophilic allylic substitution cascade to access oxazino[4,3- a ]indoles in good yields and enantio- The authors developed a gold-cat- alyzed hydroamination followed by an asymmetric nucleophilic allylic substitution cascade to access oxazino[4,3- a ]indoles in good yields and enantio- selectivities. Owing to pharmacologically active in- dole alkaloids, this rapid synthesis and asymmet- ric decoration of the polycyclic indolyl core is highly important

Autor: Giampiero Cera, Stefano Piscitelli, Michel Chairucci, Giancarlo FAbrizi, Antonella Goggiomani, R. S. Ramon, S. P. Nolan, BANDINI, MARCO

Indole chemistry continues to gain credit within organic synthesis owing to the ubiquitous presence of this heteroaromatic ring in pharmaceuticals, agrochemicals, and organic functional material science. Over the past few years, metal and metal-free

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=od______4094::ca53c37ef004588405c6ccdd6bac04c1
http://hdl.handle.net/11585/249529

Zobrazit plný text záznamu

ChemInform Abstract: One-Pot Gold-Catalyzed Synthesis of Azepino[1,2-a]indoles

Autor: Marco Bandini, Gianpiero Cera, Steven P. Nolan, Giancarlo Fabrizi, Antonella Goggiamani, Stefano Piscitelli, Michel Chiarucci, Rubén S. Ramón

Publikováno v: ChemInform. 44

2-Alkynylanilines undergo a 5-endo-dig hydroamination/dehydration sequence to provide 2-vinylindole intermediates.

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::e930a5cb488841ba604371493dad14ed
https://doi.org/10.1002/chin.201309167

Zobrazit plný text záznamu

Vyhledávací nástroje:

Upřesnit hledání