Výsledky vyhledávání - "Stefano Antoniutti"

Tetrahedral photoluminescent manganese(ii) halide complexes with 1,3-dimethyl-2-phenyl-1,3-diazaphospholidine-2-oxide as a ligand

Autor: Luca Pietrobon, Alberto Gobbo, Stefano Antoniutti, Valentina Ferraro, Jesús Castro, Marco Bortoluzzi

Publikováno v: New Journal of Chemistry. 44:571-579

Manganese(II) tetrahedral complexes having general formula [MnX2L2] (X = Cl, Br, I; L = 1,3-dimethyl-2- phenyl-1,3-diazaphospholidine-2-oxide) were isolated and characterized. The structures of the chloroand bromo-derivatives were ascertained by sing

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::4cecd312ca3366593839878c589680fe
https://doi.org/10.1039/c9nj05083c

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Synthesis and structure of the mixed phosphito-phosphine cation complex [Ru(η5-C5H5)(CO)(PPh3){P(OMe)3}]BPh4

Autor: Gabriele Albertin, Stefano Antoniutti, Jesús Castro

Publikováno v: Journal of Coordination Chemistry. 72:1652-1660

Hydrolysis of the vinylidene complex [Ru(η5-C5H5){=C=C(H)Ph} (PPh3){P(OMe)3}]BPh4 afforded the mixed-ligands carbonyl derivative [Ru(η5-C5H5)(CO)(PPh3){P(OMe)3}]BPh4. Its structure has been determined by X-ray diffraction. The compound crystallizes

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::0fb32fd94795801d049cbeee77508d73
https://doi.org/10.1080/00958972.2019.1612055

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Half-sandwich hydrazine complexes of iridium: Preparation and reactivity

Autor: Marco Bortoluzzi, Gabriele Albertin, Stefano Antoniutti, Jesús Castro

Publikováno v: Inorganica Chimica Acta. 470:139-148

Chloro complexes IrCl2(η5-C5Me5)[P(OR)3] (1) (R Me, Et) were prepared by reacting dimer [IrCl2(η5-C5Me5)]2 with phosphites in alcohol. Treatment of 1 with R1NHNH2 gave monohydrazine complexes [IrCl(η5-C5Me5)(R1NHNH2){P(OR)3}]BPh4 (2, 3, 4) [R1 H (

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::628170d6b86dce09742a10413cfdf9ac
https://doi.org/10.1016/j.ica.2017.04.016

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Ruthenium(II) pentamethylcyclopentadienyl half-sandwich carbene complexes with polypyridyl ligands

Autor: Gabriele Albertin, Mauro Trevisan, Jesús Castro, Marco Bortoluzzi, Stefano Antoniutti

Publikováno v: Journal of Organometallic Chemistry. 848:1-9

Polypyridyl complexes [RuCl(η5-C5Me5)(N–N)] (1–4) [N–N 2,2′-bipyridine (bpy) (1), 4,4′-dimethyl-2,2′-bipyridine (4,4′-Me2bpy) (2), 1,10-phenanthroline (phen) (3) and 4,7-dimethyl-1,10-phenanthroline (4,7-Me2phen) (4)] were prepared by

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::c3f34c2e2ed6e0d509a50da1644fe37c
https://doi.org/10.1016/j.jorganchem.2017.07.022

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Preparation and crystal structure of the boranehydrazine complex [RuCl(κ1-NH2NH2BPh3){P(OEt)3}4]BPh4

Autor: Jesús Castro, Stefano Antoniutti, Gabriele Albertin, Marco Bortoluzzi

Unlike what was previously reported, the reaction of the hydrazine derivative [Ru(NH2NH2)2{P(OEt)3}4](BPh4)2 with p-tolyldiazonium tetrafluoroborate in CH2Cl2 afforded the boranehydrazine complex [RuCl(κ1-NH2NH2BPh3){P(OEt)3}4]BPh4. The complex was

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::f66a07d1fd4afde00273e5fbf4fec55f
http://hdl.handle.net/10278/3714813

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Pentamethylcyclopentadienyl Half-Sandwich Hydrazine Complexes of Ruthenium: Preparation and Reactivity

Autor: Gabriele Albertin, Jesús Castro, Giulia Gasparetto, Stefano Antoniutti

Hydrazine complexes [Ru(η5-C5Me5)(NH2NHR1){P(OR)3}L]BPh4 (1–4) [R1 = H, Me, Ph; L = P(OR)3, PPh3; R = Me, Et] were prepared by the reaction of chloro compounds [RuCl(η5-C5Me5){P(OR)3}L] with hydrazines in the presence of NaBPh4. When exposed to a

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::9548dae1e2d2124898a8be7d9b86d9fa
http://hdl.handle.net/10278/3710455

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Pentamethylcyclopentadienyl osmium complexes that contain diazoalkane, dioxygen and allenylidene ligands: preparation and reactivity

Autor: Stefano Antoniutti, Francesca Sibilla, Jesús Castro, Gabriele Albertin

Diazoalkane complexes [Os(η5-C5Me5)(N2CAr1Ar2)(PPh3){P(OR)3}]BPh4 (1, 2) [R = Me (1), Et (2); Ar1 = Ar2 = Ph (a); Ar1 = Ph, Ar2 = p-tolyl (b); Ar1Ar2 = C12H8 (fluorenyl) (c)] were prepared by reacting bromo-compounds OsBr(η5-C5Me5)(PPh3){P(OR)3} wi

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::e4d8629951a3676a6ed04c706aba131d
http://hdl.handle.net/10278/3710750

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