Zobrazeno 1 - 10
of 15
pro vyhledávání: '"Stefanie V. Kohlhepp"'
Publikováno v:
Chemistry (Weinheim an Der Bergstrasse, Germany)
The dynamic equilibria of organomagnesium reagents are known to be very complex, and the relative reactivity of their components is poorly understood. Herein, a combination of DFT calculations and kinetic experiments is employed to investigate the de
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::47ff16ce9488478985f36f1edf0060a2
https://doi.org/10.1002/chem.202004164
https://doi.org/10.1002/chem.202004164
Publikováno v:
Chem. Eur. J.
The synthesis of ketones through addition of organometallic reagents to aliphatic carboxylic acids is a straightforward strategy that is limited to organolithium reagents. More desirable Grignard reagents can be activated and controlled with a bulky
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::8075cfe8adf912e95b26b52ed9c642b1
https://doi.org/10.1002/chem.202200295
https://doi.org/10.1002/chem.202200295
Publikováno v:
Chemistry – A European Journal. 28
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::50142b5a88a9f8fc7ecfde6658132e94
https://doi.org/10.1002/chem.202200294
https://doi.org/10.1002/chem.202200294
Autor:
Abraham Mendoza, Xiang Yin, Stefanie V. Kohlhepp, Rajdip Chowdhury, My Linh Tong, Zhunzhun Yu
Publikováno v:
Journal of the American Chemical Society
Photoexcited dihydronicotinamides like NADH and analogues have been found to generate alkyl radicals upon reductive decarboxylation of redox-active esters without auxiliary photocatalysts. This principle allowed aliphatic photocoupling between redox-
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::9853baaeb498300fd1fdcdd457446c8d
Publikováno v:
European Journal of Organic Chemistry. 2016:2170-2176
The marinopyrroles are a new class of natural products with highly interesting biomedical and structural features. We herein provide a concise, nitrogen-protective-group-free synthesis of marinopyrrole A, constituting the as yet most efficient route.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::63d75d3ef896d3aee394ee83144f589d
https://doi.org/10.1002/ejoc.201600147
https://doi.org/10.1002/ejoc.201600147
Autor:
Christoph Patzelt, Tanja Gulder, Alexander Pöthig, Wolfgang Bettray, Anna Ulmer, Maciej Stodulski, Stefanie V. Kohlhepp
Publikováno v:
Chemistry - A European Journal. 21:1444-1448
A tertiary hydroxy group α to a carboxyl moiety comprises a key structural motif in many bioactive substances. With the herein presented metal-free rearrangement of imides triggered by hypervalent λ(3)-iodane, an easy and selective way to gain acce
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::a6ea7db9eb96abba8d023a363bb09a42
https://doi.org/10.1002/chem.201405888
https://doi.org/10.1002/chem.201405888
Publikováno v:
Journal of Natural Products. 77:2331-2334
Fluorine-containing natural products are extremely rare. The recent report on the isolation and biological activity of the bacterial secondary metabolite 3-(3,5-di-tert-butyl-4-fluorophenyl)propionic acid was thus highly remarkable. The compound cont
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::112c511c086e18f8a4fe927e6515a136
https://doi.org/10.1021/np500643g
https://doi.org/10.1021/np500643g
Autor:
Tanja Gulder, Stefanie V. Kohlhepp
Publikováno v:
ChemInform. 47
The fluorination of organic molecules is a rapidly evolving and exciting field in synthesis, which still poses huge challenges despite the advances made in the past decades. Hypervalent iodine(III) reagents, which have already proven their versatilit
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::a52cac49f249ea3e793125c09dbc6fdf
https://doi.org/10.1002/chin.201652465
https://doi.org/10.1002/chin.201652465
Autor:
Tanja Gulder, Stefanie V. Kohlhepp
Publikováno v:
Chemical Society reviews. 45(22)
The fluorination of organic molecules is a rapidly evolving and exciting field in synthesis, which still poses huge challenges despite the advances made in the past decades. Hypervalent iodine(III) reagents, which have already proven their versatilit
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::97498075ac0cb53ace753d9ff22f8f0c
https://pubmed.ncbi.nlm.nih.gov/27417189
https://pubmed.ncbi.nlm.nih.gov/27417189
Autor:
Maciej Stodulski, Wolfgang Bettray, Christoph Patzelt, Stefanie V. Kohlhepp, Tanja Gulder, Anna Ulmer, Alexander Poethig
Publikováno v:
ChemInform. 46
The metal-free rearrangement of imides, catalyzed by in-situ formed trivalent iodine catalysts furnishes brominated α-hydroxycarboxylamides in high yields.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::86d2edbe12ea16742e084ec1a918953f
https://doi.org/10.1002/chin.201524087
https://doi.org/10.1002/chin.201524087