Zobrazeno 1 - 10
of 183
pro vyhledávání: '"Stefania Fioravanti"'
Autor:
Catarina Rapôso, Paulo Alexandre Miranda Odorissi, Stefania Fioravanti Savioli, Rafaela Chitarra Rodrigues Hell, Gustavo Ferreira Simões, Roberta R Ruela-de-Sousa, Alexandre Leite Rodrigues de Oliveira, Maria Alice da Cruz-Höfling
Publikováno v:
PLoS ONE, Vol 9, Iss 9, p e107292 (2014)
Severe accidents caused by the "armed" spider Phoneutria nigriventer cause neurotoxic manifestations in victims. In experiments with rats, P. nigriventer venom (PNV) temporarily disrupts the properties of the BBB by affecting both the transcellular a
Externí odkaz:
https://doaj.org/article/b102015418364a4db3a6d7ad3ff767f4
Publikováno v:
Molecules, Vol 21, Iss 6, p 723 (2016)
The reactivity of C-CH3 substituted N-protected aldimines in aza-Henry addition reactions was compared with that of the analogous trifluoromethylated compounds. C-Alkyl aldimines easily reacted with nitro alkanes under solvent-free conditions and in
Externí odkaz:
https://doaj.org/article/50a72d7d36104356875720d2c5ac3b79
Autor:
Laura Trulli, Ivana Beara, Lucio Pellacani, Tatjana Majkić, Neda Mimica-Dukić, Stefania Fioravanti, Luciano Saso
Publikováno v:
Medicinal Chemistry. 15:1-6
Background: A convenient approach to modulation of the inflammation has an influence on the production of inflammatory mediators – icosanoids, generated in arachidonic acid (AA) metabolism. The common therapeutic activity of non-steroidal anti-infl
Publikováno v:
European Journal of Organic Chemistry. 2018:3743-3749
Publikováno v:
Tetrahedron. 74:572-577
Trifluoromethyl aldimines derived from α-amino esters have proven to be very good starting materials to obtain the title compounds. A Ag2O-catalyzed Mannich-type/cyclization cascade reaction starting from suitable α-isocyano acetates leads to enant
Publikováno v:
European Journal of Organic Chemistry. 2017:3373-3380
The reactivity of α-nitro ketones with trifluoromethyl aldimines is studied for the first time. While under nitro-Mannich conditions only the facial stereoselectivity can be controlled, organocatalysed Mannich-type reactions allowed a complete contr
Autor:
Luca Parise, Federico Mancinelli, Laura Trulli, Stefania Fioravanti, Lucio Pellacani, Alessia Pelagalli
Publikováno v:
RSC Advances. 6:101862-101868
The synthesis of trifluoromethylated γ-amino alcohols through an eco-friendly one-pot self-catalysed Mannich-type reaction between N-protected trifluoromethyl aldimines and suitable cyclic or acyclic α,α-dialkyl aldehydes has been developed. Good
Publikováno v:
The Journal of Organic Chemistry. 80:8300-8306
A method for the synthesis of fluorinated β'-amino β-dicarbonyl compounds using a Zr-catalyzed Mannich-type reaction has been developed, starting from N-protected trifluoromethyl aldimines and cyclic or acyclic β-keto esters bearing different este
Autor:
Luca Parise, Laura Trulli, Stefania Fioravanti, Maria Cecilia Vergari, Lucio Pellacani, Alessia Pelagalli
Publikováno v:
Chirality. 27:571-575
L-α-Amino esters were considered valuable chiral starting materials in the condensation reaction with trifluoroacetaldehyde (fluoral) ethyl hemiacetal to obtain new functionalized trifluoromethyl aldimines. Starting from these latter compounds, isov
Autor:
Lucio Pellacani, Stefania Fioravanti, Simona Gasbarri, Laura Carroccia, Fabio Sciubba, Emanuele Aresu
Publikováno v:
Tetrahedron. 69:9507-9511
Chiral racemic α-diimines, tested in aziridination reactions with NsONHCO2Et, for the first time led to the synthesis of (±)-bidiaziridines, stereoselectively derived from the corresponding meso (E-s-trans-E)-α-diimines. Moreover, a minor bidiazir