Zobrazeno 1 - 3
of 3
pro vyhledávání: '"Stefani Gamboa‐Ramirez"'
Publikováno v:
Chemistry-A European Journal
Chemistry-A European Journal, 2022, pp.e202202206. ⟨10.1002/chem.202202206⟩
Chemistry-A European Journal, 2022, pp.e202202206. ⟨10.1002/chem.202202206⟩
International audience; The stereoselective copper-mediated hydroxylation of intramolecular C H bonds from tridentate ligands is reinvestigated using DFT calculations. The computational study aims at deciphering the mechanism of C H hydroxylation obt
A hybrid bioinspired catechol-alloxazine triangular nickel complex stabilizing protons and electrons
Autor:
Stefani Gamboa-Ramirez, Guillaume Rogez, Zahia Boubegtiten-Fezoua, Agnideep Das, Aurélie Guenet, Laurence Grimaud, Maylis Orio, Marine Desage-El Murr, Sylvie Choua, Hannah Jobelius, Petra Hellwig, Jésus Raya, Jules Schleinitz, Geordie Creste, Gwendal Kervern, Sylvie Ferlay, Nolwenn Le Breton
We report the design of a unique bioinspired ligand merging redox-active catechol and flavin-related alloxazine substructures. Upon coordination with a Ni(II) salt, this hybrid ligand forms a trinuclear complex containing three NiII centers and three
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::bb2a90b135b13e8a7fc76048e7cfb92e
http://xlink.rsc.org/?DOI=D1QI01131F
http://xlink.rsc.org/?DOI=D1QI01131F
Autor:
Ana Cristina García-Álvarez, Maylis Orio, Stefani Gamboa-Ramirez, Diego Martínez-Otero, Ivan Castillo
Publikováno v:
Chemical Communications
Chemical Communications, 2021, 57, pp.8608-8611. ⟨10.1039/d1cc03227e⟩
Chemical Communications, 2021, 57, pp.8608-8611. ⟨10.1039/d1cc03227e⟩
International audience; Ni 4 O 4 cubanes [(l 3-L 1 O)NiCl(MeOH)] 4 (1) and [(l 3-L 2 O)NiCl(H 2 O)] 4 (2) (L 1 OH = 1-H-2-benzimidazolylmethanol, L 2 OH = 1-methyl-2-benzimidazolylmethanol) self-assemble from commercially available 1-Hand 1-methyl-2-