Zobrazeno 1 - 10
of 50
pro vyhledávání: '"Stefan H. Wunderlich"'
Publikováno v:
Chemistry - A European Journal. 19:14687-14696
A straightforward and efficient alumination of functionalized arenes by using the frustrated Lewis pair Et3 Al and TMPMgCl⋅LiCl (TMP=2,2,6,6-tetramethylpiperidyl) has been developed. In particular, halogenated electron-rich aromatics can be smoothl
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::5393c469a67b494597a1f54e116ee549
https://doi.org/10.1002/chem.201301869
https://doi.org/10.1002/chem.201301869
Publikováno v:
Advanced Synthesis & Catalysis. 355:989-995
An improved process for the preparation of aromatic and heteroaromatic diorganozinc reagents and their subsequent reaction with electrophiles is presented. The new method, featuring the use of a 2,2,6,6-tetramethylpiperidyl (TMP) magnesium base in th
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::26f07a3a4ee9768df04ab733b830ffb4
https://doi.org/10.1002/adsc.201300049
https://doi.org/10.1002/adsc.201300049
Publikováno v:
Synthesis. 2010:2670-2678
Highly functionalized organometallics are efficiently prepared in larger quantities (up to 4 g) by directed ortho-metalation using the previously reported amide bases TMP 2 Mn·2MgCl 2 ·4LiCl (TMP = 2,2,6,6-tetramethylpiperidyl), TMP 2 Fe·2MgCl 2
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::f030b728d55b730449014fe600199e24
https://doi.org/10.1055/s-0029-1218845
https://doi.org/10.1055/s-0029-1218845
Autor:
Paul Knochel, Stefan H. Wunderlich
Publikováno v:
Chemistry - A European Journal. 16:3304-3307
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::8f194af61c505d0fb7562270c81d800d
https://doi.org/10.1002/chem.200903157
https://doi.org/10.1002/chem.200903157
Publikováno v:
Organic Process Research & Development. 14:339-345
A range of aryl and heteroaryl organometallics are efficiently prepared in THF via directed ortho metalation by using the previously reported amide bases tmpMgCl·LiCl (tmp = 2,2,6,6-tetramethylpiperidyl), tmp2Mg·2LiCl and tmp2Zn·2MgCl2·2LiCl. The
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::29e02f623611bce5c92d9bcd52e62dc5
https://doi.org/10.1021/op9002888
https://doi.org/10.1021/op9002888
Autor:
Stefan H. Wunderlich, Paul Knochel
Publikováno v:
Angewandte Chemie. 121:9897-9900
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::03bb91bca8987c3ea843b4730beb4107
https://doi.org/10.1002/ange.200905196
https://doi.org/10.1002/ange.200905196
Publikováno v:
Angewandte Chemie International Edition. 48:7256-7260
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::0ab9469afb913be6112580c2a9c594d9
https://doi.org/10.1002/anie.200903505
https://doi.org/10.1002/anie.200903505
Gesteuerte Manganierung funktionalisierter Arene und Heterocyclen mithilfe von tmp2Mn⋅2 MgCl2⋅4 LiCl
Publikováno v:
Angewandte Chemie. 121:7392-7396
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::8f47c6c6fc879078ceb6c0ee2188c561
https://doi.org/10.1002/ange.200903505
https://doi.org/10.1002/ange.200903505
Publikováno v:
European Journal of Organic Chemistry. 2009:1781-1795
New mixed Li/Mg and Li/Mg/Zn amides have been synthesized starting from readily prepared secondary amines. They allow a highly chemoselective directed magnesiation or zincation of various polyfunctional aromatics and heteroaromatics. The kinetic basi
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::934c180b857403906a06bef71d6133e4
https://doi.org/10.1002/ejoc.200801277
https://doi.org/10.1002/ejoc.200801277
Autor:
Paul Knochel, Stefan H. Wunderlich
Publikováno v:
Angewandte Chemie International Edition. 48:1501-1504
Selective C-H activation with a series of neutral aluminum trisamide bases led to a wide range of polyfunctional aryl and heteroaryl aluminum reagents. Ester and cyano groups are stable under the reaction conditions for this direct alumination, and d
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::010b0422274c02c1d78ed553d8f1749d
https://doi.org/10.1002/anie.200804966
https://doi.org/10.1002/anie.200804966