Výsledky vyhledávání - "Stanley M. Jing"

A New Paradigm in Enantioselective Cobalt Catalysis: Cationic Cobalt(I) Catalysts for Heterodimerization, Cycloaddition, and Hydrofunctionalization Reactions of Olefins

Autor: Stanley M. Jing, Vinayak Vishnu Pagar, Mahesh M. Parsutkar, Souvagya Biswas, T. V. RajanBabu, James H. Herbort

Publikováno v: Acc Chem Res

ConspectusOne of the major challenges facing organic synthesis in the 21st century is the utilization of abundantly available feedstock chemicals for fine chemical synthesis. Regio- and enantioselective union of easily accessible 1,3-dienes and other

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::a3cb6d94291c33c9635096cacc583434
https://doi.org/10.1021/acs.accounts.1c00573

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Catalytic Enantioselective Hetero-dimerization of Acrylates and 1,3-Dienes

Autor: Stanley M. Jing, T. V. RajanBabu, Vinayak Vishnu Pagar, Judith C. Gallucci, Vagulejan Balasanthiran

Publikováno v: Journal of the American Chemical Society. 139:18034-18043

1,3-Dienes are ubiquitous and easily synthesized starting materials for organic synthesis and alkyl acrylates are among the most abundant and cheap feedstock carbon sources. A practical, highly enantioselective union of these two readily available pr

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::4a001905b4ea3393d12a73d4bdfe19b4
https://doi.org/10.1021/jacs.7b10055

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TMPMg Bu(L), where L = THF, 2-MeTHF, pyridine and dimethylaminopyridine and TMP = 1,5,9-trimesityldipyrromethene: Reaction with lactide and ε-caprolactone

Autor: Stanley M. Jing, Pasco M. Wambua, Kittisak Choojun, Vagulejan Balasanthiran, Christopher B. Durr, Malcolm H. Chisholm

Publikováno v: Journal of Organometallic Chemistry. 842:74-81

The compounds TMPMgnBu(L), where L = THF, 2-MeTHF, pyridine (py) and dimethylaminopyridine (DMAP) and TMP = 1,5,9-trimesityldipyrromethene, have been synthesized and allowed to initiate polymerization with rac-lactide (rac-LA) and e-caprolactone (e �

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::ec3a6b7f994edb243a8a186e5d01f9f1
https://doi.org/10.1016/j.jorganchem.2017.05.016

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Control of Selectivity through Synergy between Catalysts, Silanes, and Reaction Conditions in Cobalt-Catalyzed Hydrosilylation of Dienes and Terminal Alkenes

Autor: Stanley M. Jing, Vagulejan Balasanthiran, Balaram Raya, T. V. RajanBabu

Publikováno v: ACS Catalysis. 7:2275-2283

Readily accessible (i-PrPDI)CoCl2 [i-Pr PDI = 2,6-bis(2,6-diisopropylphenyliminoethyl)pyridine] reacts with 2 equivalents of NaEt3BH at −78 °C in toluene to generate a catalyst that effects highly selective anti-Markovnikov hydrosilylation of the

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::d1b4672f5c3a884f008d839ffb013450
https://doi.org/10.1021/acscatal.6b03373

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Cationic Co(I)-Intermediates for Hydrofunctionalization Reactions: Regio- and Enantioselective Cobalt-Catalyzed 1,2-Hydroboration of 1,3-Dienes

Autor: Stanley M. Jing, Mahesh M. Parsutkar, Milauni M. Mehta, T. V. RajanBabu, Krishnaja Duvvuri, Judith C. Gallucci, Kendra R. Dewese

Publikováno v: Journal of the American Chemical Society. 141(18)

Much of the recent work on catalytic hydroboration of alkenes has focused on simple alkenes and styrene derivatives with few examples of reactions of 1,3- dienes, which have been reported to undergo mostly 1,4- additions to give allylic boronates. We

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::a2a4bcf7211061528f28770f9fb7b0e1
https://pubmed.ncbi.nlm.nih.gov/31020835

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