Zobrazeno 1 - 10
of 157
pro vyhledávání: '"Stanisław Pasynkiewicz"'
Autor:
Andrzej Kozioł, Antoni Pietrzykowski, Tadeusz Lis, Iwona Justyniak, Stanisław Pasynkiewicz, Lucjan B. Jerzykiewicz
Publikováno v:
Journal of Organometallic Chemistry. 767:22-26
New fluorenylnickel complexes [M(THF)n]+[Ni(η5-Flu)(η1-Flu)2]− (M = +48 Li, 1 and M = Na, 2) have been obtained in the reaction of nickel bromide with fluorenyllithium and -sodium. The X-ray molecular structures of 1 (monoclinic; P21/c) and 2 (or
Publikováno v:
Collection of Czechoslovak Chemical Communications. 72:609-617
trans-Bis[1,3-bis(2,4,6-trimethylphenyl)imidazolidin-2-ylidene]dichloronickel(II), [NiCl2(SIMes)2], was synthesized in a one-pot reaction of fluorenyllithium with nickel(II) bromide followed by the addition of 1,3-bis(2,4,6-trimethylphenyl)imidazolid
Autor:
Piotr Buchalski, Janusz Lipkowski, Stanisław Pasynkiewicz, Marek Cypryk, Antoni Pietrzykowski
Publikováno v:
Journal of Organometallic Chemistry. 691:5825-5830
A novel tetrahedral (μ3-alkylidyne)tetranickel cluster (NiCp)4(μ3-C(CH2)4CH3) (4) was obtained in the reaction of nickelocene with potassium and 1-hexene. Compound 4 was characterised by means of MS and X-ray diffraction analysis. It crystallizes i
Autor:
Monika Zdziemborska, Piotr Buchalski, Stanisław Pasynkiewicz, Kinga Suwinska, Andrzej Kozioł, Antoni Pietrzykowski
Publikováno v:
Journal of Organometallic Chemistry. 691:4080-4085
New binuclear nickelacyclic compounds 1 (η 5 -pentamethylcyclopentadienyl)(η 3 -(1-(η 5 -pentamethylcyclopentadienyl))-1-nickelafluorenyl)nickel and 2 (η 5 -pentamethylcyclopentadienyl)(η 3 -(1-(η 5 -pentamethylcyclopentadienyl))-2-phenyl-3-eth
Autor:
Tadeusz Lis, Stanisław Pasynkiewicz, Aleksandra Pęcherzewska, Włodzimierz Buchowicz, Lucjan B. Jerzykiewicz, Andrzej Kozioł, Antoni Pietrzykowski
Publikováno v:
Journal of Molecular Catalysis A: Chemical. 257:118-123
Cyclopentadienylnickel(II) complexes with N-heterocyclic carbenes [NiCp(X)(NHC)] (X = Cl, Br or CH3), combined with MAO have been used as catalysts for the polymerization of styrene. The catalytic activity of the systems depended mainly on the ease o
Publikováno v:
Inorganic Chemistry Communications. 9:375-378
A new nickelacyclic compound (η5-cyclopentadienyl)(η5-(1-(η5-cyclopentadienyl))-2-phenyl-3-ethyl-1-nickelaindenyl)nickel was synthesised in the reaction of (E)-1-lithio-1-phenyl-2-(2′-lithiophenyl)ethane with nickelocene. The compound was charac
Publikováno v:
Journal of Organometallic Chemistry. 690:1523-1528
A new metallacyclic compound (η 5 -cyclopentadienyl)(η 5 -(1-(η 5 -cyclopentadienyl)-2-phenyl-3-methyl-1-nickelaindenyl)nickel was synthesised and characterised. Its molecular and crystal structure was determined by X-ray measurements. It crystall
Polymerization of alkynes on nickelocene based catalysts: considerations on polymerization mechanism
Publikováno v:
Journal of Molecular Catalysis A: Chemical. 224:117-124
Novel nickelocene based catalysts were used for polymerization of 2-butyne, 1-phenyl-1-propyne, bis(trimethylsilyl)acetylene and trimethylsilylacetylene. The catalyst prepared in the reaction of nickelocene with organolithium compounds in the presenc
Publikováno v:
Applied Organometallic Chemistry. 18:583-588
Novel nickelocene-based catalysts were used for polymerization of diphenylacetylene and phenylacetylene. The catalyst obtained in the reaction of nickelocene with organolithium compounds in the presence of alkyne was previously isolated and fully cha
Autor:
Stanisław Pasynkiewicz, Janusz Lipkowski, Ewa Oledzka, Romana Anulewicz-Ostrowska, Antoni Pietrzykowski, Barbara Kryza-Niemiec
Publikováno v:
Inorganica Chimica Acta. 350:520-526
Results of the reactions of nickelocene with phenyl- and methyllithium in the presence of bis(trimethylsilyl)acetylene have been reported. It was found that in the reaction of nickelocene with phenyllithium and bis(trimethylsilyl)acetylene three prod