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pro vyhledávání: '"Srobona Sen"'
Publikováno v:
Organometallics. 39:4169-4173
With the view of developing electrophilic late-transition-metal catalysts, we have now synthesized [(o-(Ph2P)C6H4)2Sb(OTf)2]Pt(OTf) (2) and [(o-(iPr2P)C6H4)2Sb(OTf)2]Pt(OTf) (4) by treatment of the...
T-Shaped Gold→Stiborane Complexes as Carbophilic Catalysts: Influence of the Peripheral Substituents
Publikováno v:
Organometallics. 36:4224-4230
As part of our efforts toward the discovery of new late transition metal catalysts, we synthesized [(o-(Ph2P)C6H4)2(o-C6Cl4O2)SbPh)Au]+ (3+) and [(o-(iPr2P)C6H4)2(o-C6Cl4O2)SbPh)Au]+ (4+), two cationic bis(phosphino)gold stiborane complexes, which we
Publikováno v:
Inorganic Chemistry. 55:9162-9172
As part of our continuing interest in redox-active, anion-responsive main-group transition-metal platforms, we have investigated the effect of chloride by fluoride anion substitution on the core structure of a dinuclear AuSb platform. Starting from [
Autor:
Srobona Sen, François P. Gabbaï
Publikováno v:
Chemical Communications. 53:13356-13358
We describe the synthesis of an ambiphilic phosphine/H-bond donor ligand featuring a trifluoroacetamide functionality, its coordination to gold(i) chloride, and its application as a self-activating catalyst for the cyclization of propargylamides.
Publikováno v:
Journal of the American Chemical Society. 140(30)
In search of ligand platforms, which can be used to remotely control the catalytic activity of a transition metal, we have investigated the coordination noninnocence of ambiphilic L2/Z-type ligands containing a trifluorostiborane unit as a Lewis acid