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Autor:
Khalid Iftikhar, Aabid Bashir Ganaie
Publikováno v:
ACS Omega, Vol 6, Iss 33, Pp 21207-21226 (2021)
ACS Omega
ACS Omega
Heteroleptic homo dinuclear complexes [Sm(fod)3(μ-bpp)Sm(fod)3] and [Eu(fod)3(μ-bpp)Eu(fod)3] and their diamagnetic analogue [Lu(fod)3(μ-bpp)Lu(fod)3] (fod is the anion of 6,6,7,7,8,8,8- heptafluoro-2,2-dimethyl-3,5-octanedione (Hfod) and bpp is 2
Autor:
Yaxing Wang, Yugang Zhang, Tong Zhou, Kai Li, Zhifang Chai, Yuan Zhao, Hailong Zhang, Shu-Xian Hu, Qing Zou
Publikováno v:
Inorganic Chemistry. 60:8984-8989
We report the synthesis, single-crystal structure, solid-state ultraviolet-visible-near-infrared spectroscopy, and theoretical calculations on the first trivalent plutonium crown ether inclusion complex, [(H3O)(18-crown-6)][Pu(H2O)4(18-crown-6)](ClO4
Autor:
Alvaro Muñoz-Castro, Zhong-Ming Sun, Nikolay V. Tkachenko, Hong-Lei Xu, Alexander I. Boldyrev
Publikováno v:
Angewandte Chemie. 133:10078-10083
Since [Sn8 ]6- was discovered from the solid-state phase in 2000, its solution chemistry has been elusive due to the high charges and chemical activity. Herein, we report the synthesis and characterization of an inverse sandwich-type cluster dimer {[
Autor:
N. B. Ivakha, Olena Trunova, Nataliia V. Rusakova, Oleksandra Berezhnytska, Oleksandr Rohovtsov
Publikováno v:
Ukrainian Chemistry Journal. 87:65-76
New ytterbium (III) compounds with β-diketones (2,7-dimethyl-octene-1-dione-3,5 and 2,6-dimethylheptene-1-dione-3,5) and their derivatives with phenanthroline have been synthesized. The composition and chemical structure of the obtained complexes ha
Publikováno v:
Journal of the Iranian Chemical Society. 18:2381-2388
A novel erbium material with a fascinated mercury bromide cluster (Hg11Br34)12– anion, i.e., {[Er2(H2O)4(HIA)6]2n}(nHg11Br34)(nHgBr2)·4nH2O (denoted as 1 and HIA indicates the isonicotinic acid molecule), was successfully synthesized from a solvot
Publikováno v:
Russian Journal of Coordination Chemistry. 47:58-65
Three nickel(II), manganese(II) and cadmium(II) complexes, [NiL2] (I), [MnL2] (II) and [Cd(HL)2(NO3)]·NO3 (III), derived from 4-bromo-N'-(1-(pyridin-2-yl)ethylidene)benzohydrazide (HL) were prepared and characterized by IR and UV spectra. Structures
Autor:
Daniel Reta, Enrique Colacio, Julio Corredoira-Vázquez, Jesús Sanmartín-Matalobos, Ana M. García-Deibe, Matilde Fondo
Publikováno v:
Dalton Transactions. 50:15878-15887
The mononuclear complexes [Dy(3Br,5Cl-H3L1,1,4)(D)]·solvate (D = H2O, solvate = 0.25MeOH, 1W·0.25MeOH; D = Py without solvate, 1Py), and [Dy(3NO2,5Br-H3L1,1,4)(H2O)] (2W) were isolated. The crystal structures of 1W·0.25MeOH, 1Py and 2W·2CH3C6H5 s
Autor:
Armandina M. L. Lopes, Albano N. Carneiro Neto, Paula Brandão, Alexandre M. P. Botas, Rute A. S. Ferreira, Alolika Sarkar, João P. Araújo, Rupam Sen, Zhi Lin, Sanchayeeta Paul
Publikováno v:
CrystEngComm. 23:4143-4151
A new series of 3D lanthanide (Ln) frameworks has been synthesized with the general formula [{Ln(L)(H2O)}·H2O]n (where Ln = La(1), Tb(2) and Dy(3); L = (HO)OC6H2(CH2COO)2; H3L = 2,5-dihydroxy-1,4-benzenediacetic acid = DHBDA). All the crystals were